Highly stereoselective ring-opening addition of terminal acetylenes to bicyclic olefins catalyzed by nickel complexes

被引：92
作者：
Rayabarapu, DK [1 ]
Chiou, CF [1 ]
Cheng, CH [1 ]
机构：
[1] Natl Tsing Hua Univ, Dept Chem, Hsinchu 300, Taiwan
来源：
ORGANIC LETTERS | 2002年 / 4卷 / 10期
关键词：
D O I：
10.1021/ol025731d
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
[GRAPHICS] Treatment of 7-oxa- and 7-azabonzonorbornadienes with terminal acetylenes in the presence of Ni(dppe)Cl-2, ZnCl2, and Zn powder in toluene at 90 degreesC afforded the corresponding cis-2-alkynyl-1,2-dihydronaphthalene derivatives in moderate to excellent yields with remarkably high stereoselectivity.
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页码：1679 / 1682
页数：4
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