Gas-phase tropospheric chemistry of volatile organic compounds .1. Alkanes and alkenes

被引:1154
作者
Atkinson, R [1 ]
机构
[1] UNIV CALIF RIVERSIDE,STATEWIDE AIR POLLUT RES CTR,DEPT CHEM,RIVERSIDE,CA 92521
关键词
alkanes; alkenes; kinetics; reaction mechanisms; reaction products; hydroxyl radical; nitrate radical; ozone;
D O I
10.1063/1.556012
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Literature data (through mid-1996) concerning the gas-phase reactions of alkanes and alkenes (including isoprene and monoterpenes) leading to their first generation products are reviewed and evaluated for tropospheric conditions. The recommendations of the most recent IUPAC evaluation [J. Phys. Chem. Ref. Data, 26, No. 3 (1997)] are used for the less than or equal to C-3 organic compounds, unless more recent data necessitates reevaluation. The most recent review and evaluation of Atkinson [J. Phys. Chem. Ref. Data, Monograph 2, 1 (1994)] concerning the kinetics of the reactions of OH radicals, NO3 radicals, and O-3 is also updated for these two classes of volatile organic compounds. (C) 1997 American Institute of Physics and American Chemical Society.
引用
收藏
页码:215 / 290
页数:76
相关论文
共 413 条
[31]   KINETICS OF THE REACTIONS OF OH RADICALS WITH NORMAL-ALKANES AT 299-K+/-2-K [J].
ATKINSON, R ;
ASCHMANN, SM ;
CARTER, WPL ;
WINER, AM ;
PITTS, JN .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1982, 14 (07) :781-788
[32]   GAS-PHASE REACTION OF NO2 WITH ALKENES AND DIALKENES [J].
ATKINSON, R ;
ASCHMANN, SM ;
WINER, AM ;
PITTS, JN .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1984, 16 (06) :697-706
[33]   KINETICS OF THE GAS-PHASE REACTIONS OF CL ATOMS WITH CHLOROETHENES AT 298+/-2-K AND ATMOSPHERIC-PRESSURE [J].
ATKINSON, R ;
ASCHMANN, SM .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1987, 19 (12) :1097-1105
[34]   KINETICS OF THE GAS-PHASE REACTION OF CL ATOMS WITH A SERIES OF ORGANICS AT 296+/- 2K AND ATMOSPHERIC-PRESSURE [J].
ATKINSON, R ;
ASCHMANN, SM .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1985, 17 (01) :33-41
[35]   EXTENT OF H-ATOM ABSTRACTION FROM THE REACTION OF THE OH RADICAL WITH 1-BUTENE UNDER ATMOSPHERIC CONDITIONS [J].
ATKINSON, R ;
TUAZON, EC ;
CARTER, WPL .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1985, 17 (07) :725-734
[36]   EFFECTS OF RING STRAIN ON GAS-PHASE RATE CONSTANTS .3. NO3 RADICAL REACTIONS WITH CYCLOALKENES [J].
ATKINSON, R ;
ASCHMANN, SM ;
LONG, WD ;
WINER, AM .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1985, 17 (09) :957-966
[37]   RATE CONSTANTS FOR THE REACTION OF OH RADICALS WITH A SERIES OF ALKANES AND ALKENES AT 299 +/- 2-K [J].
ATKINSON, R ;
ASCHMANN, SM ;
WINER, AM ;
PITTS, JN .
INTERNATIONAL JOURNAL OF CHEMICAL KINETICS, 1982, 14 (05) :507-516
[38]   FORMATION OF OH RADICALS IN THE GAS-PHASE REACTIONS OF O3 WITH A SERIES OF TERPENES [J].
ATKINSON, R ;
ASCHMANN, SM ;
AREY, J ;
SHOREES, B .
JOURNAL OF GEOPHYSICAL RESEARCH-ATMOSPHERES, 1992, 97 (D5) :6065-6073
[39]   PRODUCTS OF THE GAS-PHASE REACTIONS OF O-3 WITH ALKENES [J].
ATKINSON, R ;
TUAZON, EC ;
ASCHMANN, SM .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 1995, 29 (07) :1860-1866
[40]   KINETICS AND MECHANISMS OF THE GAS-PHASE REACTIONS OF OZONE WITH ORGANIC-COMPOUNDS UNDER ATMOSPHERIC CONDITIONS [J].
ATKINSON, R ;
CARTER, WPL .
CHEMICAL REVIEWS, 1984, 84 (05) :437-470