Ruthenium-Catalyzed Alkoxycarbonylation of Alkenes with Paraformaldehyde as a Carbon Monoxide Substitute

被引：24

作者：

Liu, Qiang ^{[1
]}

Wu, Lipeng ^{[1
]}

Jackstell, Ralf ^{[1
]}

Beller, Matthias ^{[1
]}

机构：

[1] Univ Rostock, Leibniz Inst Katalyse, D-18059 Rostock, Germany

来源：

CHEMCATCHEM | 2014年 / 6卷 / 10期

关键词：

alkenes; alkoxycarbonylation; C1 building blocks; formaldehyde; ruthenium; METHYL-FORMATE; INTERNAL ALKENES; ALCOHOLS; OLEFINS; HYDROESTERIFICATION; CARBONYLATION; FORMALDEHYDE; HYDROFORMYLATION; EFFICIENT; HYDROHYDROXYALKYLATION;

D O I：

10.1002/cctc.201402304

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The first efficient use of paraformaldehyde in the alkoxycarbonylation of alkenes is reported. Using a combination of readily available [Ru-3(CO)(12)] and PCy3 (Cy=cyclohexyl) as catalyst, industrially important esters are produced in good to high yield (up to 90%) at relatively low temperature. This new method is applicable to a series of alkenes and alcohols. Moreover, the use of formaldehyde as the carbonyl source provides the potential to avoid both reliance on CO in carbonylation reactions, and the requirement for special high-pressure reactors.

引用

页码：2805 / 2809

页数：5

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