The non-covalent assembly of benzene-bridged metallosalphen dimers: photoconductive tapes with large carrier mobility and spatially distinctive conduction anisotropy

被引：9
作者：
Chen, Long [2 ]
Wang, Lu [3 ]
Gao, Xingfa [3 ]
Nagase, Shigeru [3 ]
Honsho, Yoshihito [1 ]
Saeki, Akinori [1 ]
Seki, Shu [1 ,4 ]
Jiang, Donglin [2 ,4 ]
机构：
[1] Osaka Univ, Grad Sch Engn, Dept Appl Chem, Suita, Osaka 5650871, Japan
[2] Inst Mol Sci, Dept Mat Mol Sci, Okazaki, Aichi 4478787, Japan
[3] Inst Mol Sci, Dept Theoret & Computat Mol Sci, Okazaki, Aichi 4448585, Japan
[4] Japan Sci & Technol Agcy, JST, Precursory Res Embryon Sci & Technol PRESTO, Chiyoda Ku, Tokyo 1020075, Japan
来源：
CHEMICAL COMMUNICATIONS | 2009年 / 21期
关键词：
ELECTRON-TRANSFER; CHARGE-CARRIERS; NANOTUBES; TRANSPORT; POLYMERS; COMPLEX; DONOR;
D O I：
10.1039/b904337c
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A newly synthesized benzene-bridged metallosalphen dimer tailored with aliphatic chains is demonstrated for the solution-processed assembly of a pi-electronic tape, which shows a large intrinsic carrier mobility, is spatially anisotropic in conduction, forms p- or n-type semiconductors tunable upon doping, is photoconductive and is capable of repetitive switching with large on-off ratios.
引用
收藏
页码：3119 / 3121
页数：3
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