Formation of a Novel P,C-Cage Ligand via a P-C5Me5-Substituted Li/Cl Phosphinidenoid Complex

被引：38

作者：

Bode, Maren ^{[1
]}

Daniels, Joerg ^{[1
]}

Streubel, Rainer ^{[1
]}

机构：

[1] Univ Bonn, Inst Anorgan Chem, D-53121 Bonn, Germany

来源：

ORGANOMETALLICS | 2009年 / 28卷 / 16期

关键词：

CHEMISTRY; SILYLLITHIUM; SILYLENOIDS; REACTIVITY;

D O I：

10.1021/om900331g

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The novel P,C-cage ligand in the dinuclear tungsten complex 3 was obtained by reaction of the Li/Cl phosphinidenoid complex 2, characterized by, NMR spectroscopy, at low, temperature; complex 3 was characterized by elemental analysis and NMR, IR, and MS studies and by single-crystal X-ray diffraction.

引用

收藏

页码：4636 / 4638

页数：3

相关论文

共 21 条

[1]

[Anonymous], 1965, ANGEW CHEM-GER EDIT, V77, P1

[2] Crystalline Na-Si(NN) derivatives [Si(NN) = Si{(NCH2tBu)2C6H4-1,2}]:: the silylenoid [Si(NN)OMe]-, the dianion [(NN)Si-Si(NN)]2-, and the radical anion c-[Si(NN)]3- [J].

Antolini, F ;

Gehrhus, B ;

Hitchcock, PB ;

Lappert, MF .

CHEMICAL COMMUNICATIONS, 2005, (40) :5112-5114

[3] The electrophilic nature of carbenoids, nitrenoids, and oxenoids [J].

Boche, G ;

Lohrenz, JCW .

CHEMICAL REVIEWS, 2001, 101 (03) :697-756

[4] Synthesis of novel O,P,C-Cage complexes via thermal c-o ring opening of an oxaphosphirane W(CO)5 complex [J].

Bode, Maren ;

Schnakenburg, Gregor ;

Jones, Peter G. ;

Streubel, Rainer .

ORGANOMETALLICS, 2008, 27 (11) :2664-2667

[5] A study of NMR chemical shielding in 5-coordinate phosphorus compounds (phosphoranes) [J].

Chesnut, DB ;

Quin, LD .

TETRAHEDRON, 2005, 61 (52) :12343-12349

[6] Silyl anions or silylenoids?: A DFT study of silyllithium compounds with π-donating substituents [J].

Flock, M ;

Marschner, C .

CHEMISTRY-A EUROPEAN JOURNAL, 2005, 11 (16) :4635-4642

[7] endolexo preferences for double bonds in three-membered rings including phosphorus compounds [J].

Goumans, TPM ;

Ehlers, AW ;

Lammertsma, K ;

Würthwein, EU .

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2003, 2003 (15) :2941-2946

[8] INTERMEDIATES OF ALPHA-ELIMINATIONS [J].

KIRMSE, W .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1965, 4 (01) :1-&

[9] CHEMISTRY OF STABLE ALPHA-HALOGENOORGANOLITHIUM COMPOUNDS AND MECHANISM OF CARBENOID REACTIONS [J].

KOBRICH, G .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1967, 6 (01) :41-&

[10] The Quest for Ring Opening of Oxaphosphirane Complexes: A Coupled-Cluster and Density Functional Study of CH3PO Isomers and Their Cr(CO)5 Complexes [J].

Krahe, Oliver ;

Neese, Frank ;

Streubel, Rainer .

CHEMISTRY-A EUROPEAN JOURNAL, 2009, 15 (11) :2594-2601