SnO2 nanocrystals in SiO2:: A wide-band-gap quantum-dot system

被引:139
作者
Chiodini, N [1 ]
Paleari, A [1 ]
Di Martino, D [1 ]
Spinolo, G [1 ]
机构
[1] Univ Milano Bicocca, Dept Mat Sci, Ist Nazl Fis Mat, I-20125 Milan, Italy
关键词
D O I
10.1063/1.1503154
中图分类号
O59 [应用物理学];
学科分类号
摘要
Nanoclusters of crystalline SnO2 have been grown in glass, starting from tin-doped silica prepared by a sol-gel method. Based upon a particular choice of molecular precursors, nanocrystallites with a mean radius of about 1 nm and a quite narrow size dispersion were obtained, resulting in wide-band-gap (>4 eV) quantum dots (QDs). In this system, differently from other semiconductor-doped glasses, both the glassy host and the nanophase are oxides of IV-group elements. Owing to their thermochemical compatibility, the two phases give stable optical-grade glass ceramics with potential applications in photonics, opening up the field to technological employments of wide-band-gap QDs. (C) 2002 American Institute of Physics.
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页码:1702 / 1704
页数:3
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