Resolving ruthenium: XPS studies of common ruthenium materials

被引：920

作者：

Morgan, David J. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff Catalysis Inst, Cardiff CF10 3AT, S Glam, Wales

来源：

SURFACE AND INTERFACE ANALYSIS | 2015年 / 47卷 / 11期

关键词：

ruthenium; XPS; fitting; RuO2; RuCl3; anhydrous; hydroxide; RAY PHOTOELECTRON-SPECTROSCOPY; X-RAY; ELECTRONIC-STRUCTURE; LACTIC-ACID; SURFACE; RUO2; OXIDATION; RUO2(110); OXYGEN; OXIDES;

D O I：

10.1002/sia.5852

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

X-ray photoelectron spectroscopy (XPS) utilising monochromatic Al K radiation has been employed to study metallic ruthenium and the catalytically and technologically important ruthenium compounds RuO2, RuCl3, Ru(NO)(NO3)(3) and Ru(AcAc)(3). The results improve on the accuracy of already published Ru(3d) binding energies, expand known Ru(3p) binding energies and also report spin-orbit splitting for the core levels. For RuO2, the difference between anhydrous and hydrated samples is explored, and the effect on curve fitting such spectra is discussed. Analysis of RuCl3 has allowed, for the first time, the positive identification of Ru(OH)(3) by XPS. Copyright (c) 2015 John Wiley & Sons, Ltd.

引用

页码：1072 / 1079

页数：8

共 75 条

[11] CHEMISORPTIVE REPLACEMENT OF SURFACE OXYGEN BY HYDROGEN HALIDES (HCL AND HBR) AT PB(110) SURFACES - PHOTOELECTRON SPECTROSCOPIC AND KINETIC EVIDENCE FOR A METASTABLE CHLORIDE OVERLAYER [J].

BLAKE, PG ;

CARLEY, AF ;

DICASTRO, V ;

ROBERTS, MW .

JOURNAL OF THE CHEMICAL SOCIETY-FARADAY TRANSACTIONS I, 1986, 82 :723-737

[12] High-pressure oxidation of ruthenium as probed by surface-enhanced Raman and X-ray photoelectron spectroscopies [J].

Chan, HYH ;

Takoudis, CC ;

Weaver, MJ .

JOURNAL OF CATALYSIS, 1997, 172 (02) :336-345

[13] COMPLEXES OF PLATINUM METALS .8. ELECTRON-SPECTROSCOPY FOR CHEMICAL-ANALYSIS STUDIES OF SOME NITROSYL, ARYLDIAZO, AND ARYLDIIMINE DERIVATIVES OF RUTHENIUM, OSMIUM, RHODIUM, AND IRIDIUM [J].

CLARK, DT ;

WOOLSEY, IS ;

ROBINSON, SD ;

LAING, KR ;

WINGFIELD, JN .

INORGANIC CHEMISTRY, 1977, 16 (05) :1201-1206

[14] THE ELECTRONIC-STRUCTURE OF BI2-XGDXRU2O7 AND RUO2 - A STUDY BY ELECTRON-SPECTROSCOPY [J].

COX, PA ;

GOODENOUGH, JB ;

TAVENER, PJ ;

TELLES, D ;

EGDELL, RG .

JOURNAL OF SOLID STATE CHEMISTRY, 1986, 62 (03) :360-370

[15] XPS and FTIR study of Ru/Al2O3 and Ru/TiO2 catalysts:: Reduction characteristics and interaction with a methane-oxygen mixture [J].

Elmasides, C ;

Kondarides, DI ;

Grünert, W ;

Verykios, XE .

JOURNAL OF PHYSICAL CHEMISTRY B, 1999, 103 (25) :5227-5239

[16] Unraveling the oxidation of Ru using XPS [J].

Ernst, M. A. ;

Sloof, W. G. .

SURFACE AND INTERFACE ANALYSIS, 2008, 40 (3-4) :334-337

[17] An X-ray photoelectron spectroscopy study of hydrous ruthenium oxide powders with various water contents for supercapacitors [J].

Foelske, A ;

Barbieri, O ;

Hahn, M ;

Kötz, R .

ELECTROCHEMICAL AND SOLID STATE LETTERS, 2006, 9 (06) :A268-A272

[18] ESCA STUDIES ON CHARGE-DISTRIBUTION IN SOME DINITROGEN COMPLEXES OF RHENIUM, IRIDIUM, RUTHENIUM, AND OSMIUM [J].

FOLKESSON, B .

ACTA CHEMICA SCANDINAVICA, 1973, 27 (01) :287-302

[19] Surface reduction of ruthenium compounds with long exposure to an X-ray beam in photoelectron spectroscopy [J].

Froment, P ;

Genet, MJ ;

Devillers, M .

JOURNAL OF ELECTRON SPECTROSCOPY AND RELATED PHENOMENA, 1999, 104 (1-3) :119-126

[20] Following the Evolution of Ru/Activated Carbon Catalysts during the Decomposition-Reduction of the Ru(NO)(NO3)3 Precursor [J].

Garcia-Garcia, Francisco R. ;

Fernandez-Garcia, Marcos ;

Newton, Mark A. ;

Rodriguez-Ramos, Inmaculada ;

Guerrero-Ruiz, Antonio .

CHEMCATCHEM, 2013, 5 (08) :2446-2452

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