Nitrogen and Hydrogen Adsorption by an Organic Microporous Crystal

被引：127

作者：

Msayib, Kadhum J. ^{[1
]}

Book, David ^{[3
]}

Budd, Peter M. ^{[2
]}

Chaukura, Nhamo ^{[2
]}

Harris, Kenneth D. M. ^{[1
]}

Helliwell, Madeleine ^{[2
]}

Tedds, Steven ^{[3
]}

Walton, Allan ^{[3
]}

Warren, John E. ^{[4
]}

Xu, Mingcan ^{[1
]}

McKeown, Neil B. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 AT, S Glam, Wales

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[3] Univ Birmingham, Sch Met & Mat, Coll Engn & Phys Sci, Birmingham B15 2TT, W Midlands, England

[4] CCLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 18期

基金：

英国工程与自然科学研究理事会;

关键词：

adsorption; hydrogen storage; interconnectivity; microporous materials; organic zeolites; STORAGE; POLYMERS; CHEMISTRY; SORPTION; CAVITIES; DESIGN; NETS; UREA; GAS;

D O I：

10.1002/anie.200900234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3 ,4,4 -tetra(trimethylsilylethynyl) biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3273 / 3277

页数：5

共 77 条

[41]

Mascal M., 1996, ANGEW CHEM, V108, P2348

[42]

McKeown N. B., 2006, ANGEW CHEM, V118, P1836

[43] A phthalocyanine clathrate of cubic symmetry containing interconnected solvent-filled voids of nanometer dimensions [J].

McKeown, NB ;

Makhseed, S ;

Msayib, KJ ;

Ooi, LL ;

Helliwell, M ;

Warren, JE .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (46) :7546-7549

[44] Towards polymer-based hydrogen storage materials: Engineering ultramicroporous cavities within polymers of intrinsic microporosity [J].

McKeown, NB ;

Ghanem, BS ;

Msayib, KJ ;

Budd, PM ;

Tattershall, CE ;

Mahmood, K ;

Tan, S ;

Book, D ;

Langmi, HW ;

Walton, A .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (11) :1804-1807

[45] Microporous polymers as potential hydrogen storage materials [J].

McKeown, Neil B. ;

Budd, Peter M. ;

Book, David .

MACROMOLECULAR RAPID COMMUNICATIONS, 2007, 28 (09) :995-1002

[46] Polymers of intrinsic microporosity (PIMs): organic materials for membrane separations, heterogeneous catalysis and hydrogen storage [J].

McKeown, Neil B. ;

Budd, Peter M. .

CHEMICAL SOCIETY REVIEWS, 2006, 35 (08) :675-683

[47] Gas storage in nanoporous materials [J].

Morris, Russell E. ;

Wheatley, Paul S. .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2008, 47 (27) :4966-4981

[48] HIGH DIASTEREOFACIAL SELECTIVITY IN NUCLEOPHILIC ADDITIONS TO CHIRAL ACYLSILANES [J].

NAKADA, M ;

URANO, Y ;

KOBAYASHI, S ;

OHNO, M .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1988, 110 (14) :4826-4827

[49] Electrochemical and ferromagnetic couplings in 4,4′,4"-( 1,3,5-benzenetriyl)tris(phenoxyl) radical formation [J].

Nishide, H ;

Doi, R ;

Oyaizu, K ;

Tsuchida, E .

JOURNAL OF ORGANIC CHEMISTRY, 2001, 66 (05) :1680-1685

[50] CH/π hydrogen bonds in crystals [J].

Nishio, M .

CRYSTENGCOMM, 2004, 6 :130-158

← 1 2 3 4 5 6 7 8 →