Nitrogen and Hydrogen Adsorption by an Organic Microporous Crystal

被引：127

作者：

Msayib, Kadhum J. ^{[1
]}

Book, David ^{[3
]}

Budd, Peter M. ^{[2
]}

Chaukura, Nhamo ^{[2
]}

Harris, Kenneth D. M. ^{[1
]}

Helliwell, Madeleine ^{[2
]}

Tedds, Steven ^{[3
]}

Walton, Allan ^{[3
]}

Warren, John E. ^{[4
]}

Xu, Mingcan ^{[1
]}

McKeown, Neil B. ^{[1
]}

机构：

[1] Cardiff Univ, Sch Chem, Cardiff CF10 AT, S Glam, Wales

[2] Univ Manchester, Sch Chem, Manchester M13 9PL, Lancs, England

[3] Univ Birmingham, Sch Met & Mat, Coll Engn & Phys Sci, Birmingham B15 2TT, W Midlands, England

[4] CCLRC Daresbury Lab, Warrington WA4 4AD, Cheshire, England

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2009年 / 48卷 / 18期

基金：

英国工程与自然科学研究理事会;

关键词：

adsorption; hydrogen storage; interconnectivity; microporous materials; organic zeolites; STORAGE; POLYMERS; CHEMISTRY; SORPTION; CAVITIES; DESIGN; NETS; UREA; GAS;

D O I：

10.1002/anie.200900234

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Quick on the uptake: Following its identification during a targeted search, the intriguing crystal structure of 3,3 ,4,4 -tetra(trimethylsilylethynyl) biphenyl was investigated. Simple removal of the included solvent provides an organic crystal with an open microporous structure that has a striking similarity to that of zeolite A (see picture). Reversible adsorption of nitrogen and hydrogen gases at 77 K confirms that the microporosity is permanent. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：3273 / 3277

页数：5

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