Hydrocarbon Separations in Metal-Organic Frameworks

被引：527
作者：
Herm, Zoey R. [1 ]
Bloch, Eric D. [1 ]
Long, Jeffrey R. [1 ]
机构：
[1] Univ Calif Berkeley, Dept Chem, Berkeley, CA 94720 USA
来源：
CHEMISTRY OF MATERIALS | 2014年 / 26卷 / 01期
关键词：
metal-organic frameworks; hydrocarbons; gas separations; POLYCYCLIC AROMATIC-HYDROCARBONS; HIGHLY SELECTIVE SEPARATION; LIQUID-PHASE ADSORPTION; ZEOLITIC IMIDAZOLATE FRAMEWORKS; GAS-CHROMATOGRAPHIC SEPARATION; ALKANE ISOMER MIXTURES; P-XYLENE SELECTIVITY; MOLECULAR SIMULATION; CU-BTC; KINETIC SEPARATION;
D O I：
10.1021/cm402897c
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
New materials capable of separating mixtures of saturated, unsaturated, and aromatic hydrocarbons can enable more efficient industrial processes and cleaner energy. Outstanding challenges in hydrocarbon separations stem from the similar structures, properties, and reactivities of the molecules comprising many of these mixtures. With high surface areas, tunable pore geometries, and adjustable surface functionality, metal-organic frameworks hold tremendous promise for effecting previously difficult or impossible separations. In this review, we provide a comprehensive account of the metal organic frameworks that have been investigated for hydrocarbon separations within the context of their potential relevance for separating various industrial alkane-, alkene-, and aromatic-containing mixtures.
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收藏
页码：323 / 338
页数：16
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