N,P-co-doped carbon nanowires prepared from bacterial cellulose for supercapacitor

被引:87
作者
Hu, Zhaoxia [1 ,2 ]
Li, Shuoshuo [1 ,2 ]
Cheng, Pengpeng [1 ,2 ]
Yu, Wendan [1 ,2 ]
Li, Ruchun [1 ,2 ]
Shao, Xiaofeng [1 ,2 ]
Lin, Worong [1 ,2 ]
Yuan, Dingsheng [1 ,2 ]
机构
[1] Jinan Univ, Dept Chem, Guangzhou 510632, Guangdong, Peoples R China
[2] Jinan Univ, Inst Nanochem, Guangzhou 510632, Guangdong, Peoples R China
基金
中国国家自然科学基金;
关键词
POROUS CARBON; SUPERIOR PERFORMANCE; NITROGEN; NANOFIBERS; CAPACITANCE; PHOSPHORUS; ELECTRODES; ULTRALIGHT; DEVICES; METAL;
D O I
10.1007/s10853-015-9576-x
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report a low cost, environmentally friendly nitrogen (N) and phosphorus (P) co-doped porous carbon nanowires derived from bacterial cellulose which acts as the efficient electrode materials for the supercapacitor. The as-prepared material exhibits a large specific capacitance of 258 F/g at a current density of 1 A/g and an excellent cycling stability of 30000 cycles. The excellent electrochemical performance is attributed to the synergistic effect of P and N doping in carbon nanowires and the unique three-dimensional network and porous structure. In addition, a symmetric supercapacitor has been fabricated by exploiting the as-prepared material as a positive electrode and negative electrode. The as-fabricated symmetric supercapacitor shows promising energy density of 5.4 Wh/kg at high power density of 200 W/kg, along with an excellent cycle stability of 87 % specific capacitance retention after 6000 cycles. The advanced specific capacitance and excellent cycle stability of the carbon nanowires imply that it could be a potential candidate in commercial applications of supercapacitors.
引用
收藏
页码:2627 / 2633
页数:7
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