Effect of doping on photosensitivity of sol-gel derived silica glasses

被引:0
作者
Leyderman, A [1 ]
Arcos, D [1 ]
Lee, CYC [1 ]
机构
[1] Univ Puerto Rico, Dept Phys, Mayaguez, PR 00680 USA
来源
PHOTOREFRACTIVE FIBER AND CRYSTAL DEVICES: MATERIALS, OPTICAL PROPERTIES, AND APPLICATIONS VII, AND OPTICAL DATA STORAGE | 2002年 / 4459卷
关键词
sol-gel; germano-silicate glass; photosensitivity;
D O I
10.1117/12.454040
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Effect of doping on the UV optical absorption in silica sol gel glasses is studied through investigating the variation of structure and photochemical transformation of oxygen deficient centers. Optical absorption spectra of silica and lithium, aluminum germano-silica sol gel glasses reveal a change in the structure with changing the concentration of complements, specifically transformation of oxygen deficient centers and formation of new centers. Photosensitive response in germano-silicate glasses is enhanced by lithium ions, which act efficiently as charge compensators. Improvement on the change of refractive index is shown in samples containing lithium.
引用
收藏
页码:210 / 218
页数:9
相关论文
共 27 条
[1]   X-RAY-INDUCED LUMINESCENCE IN CRYSTALLINE SIO2 [J].
ALONSO, PJ ;
HALLIBURTON, LE ;
KOHNKE, EE ;
BOSSOLI, RB .
JOURNAL OF APPLIED PHYSICS, 1983, 54 (09) :5369-5375
[2]  
BRINKER CJ, 1990, SOL GEL SCI PHYSICS
[3]   ULTRAVIOLET AND INFRARED ABSORPTION OF FUSED GERMANIA [J].
COHEN, AJ ;
SMITH, HL .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1958, 7 (04) :301-306
[4]   Difference in the behavior of oxygen deficient defects in Ge-doped silica optical fiber preforms under ArF and KrF excimer laser irradiation [J].
Essid, M ;
Brebner, JL ;
Albert, J ;
Awazu, K .
JOURNAL OF APPLIED PHYSICS, 1998, 84 (08) :4193-4197
[5]   Laser-power dependence of absorption changes in Ge-doped SiO2 glass induced by a KrF excimer laser [J].
Fujimaki, M ;
Yagi, K ;
Ohki, Y ;
Nishikawa, H ;
Awazu, K .
PHYSICAL REVIEW B, 1996, 53 (15) :9859-9862
[6]   Excited-state absorption measurement in Ge-doped SiO2 glass [J].
Fujimaki, M ;
Seol, KS ;
Ohki, Y .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (06) :2913-2915
[7]   Energy states of Ge-doped SiO2 glass estimated through absorption and photoluminescence [J].
Fujimaki, M ;
Ohki, Y ;
Nishikawa, H .
JOURNAL OF APPLIED PHYSICS, 1997, 81 (03) :1042-1046
[8]   RADIATION EFFECTS IN CRYSTALLINE SIO2 - THE ROLE OF ALUMINUM [J].
HALLIBURTON, LE ;
KOUMVAKALIS, N ;
MARKES, ME ;
MARTIN, JJ .
JOURNAL OF APPLIED PHYSICS, 1981, 52 (05) :3565-3574
[9]   NATURE AND ORIGIN OF THE 5-EV BAND IN SIO2-GEO2 GLASSES [J].
HOSONO, H ;
ABE, Y ;
KINSER, DL ;
WEEKS, RA ;
MUTA, K ;
KAWAZOE, H .
PHYSICAL REVIEW B, 1992, 46 (18) :11445-11451
[10]   Defect formation in SiO2:GeO2 glasses studied by irradiation with excimer laser light [J].
Hosono, H ;
Kawazoe, H ;
Nishii, J .
PHYSICAL REVIEW B, 1996, 53 (18) :11921-11923