Processing of preceramic polymer to low density silicon carbide foam

被引：71

作者：

Jana, Prasanta ^{[1
]}

Zera, Emanuele ^{[1
]}

Soraru, Gian Domenico ^{[1
]}

机构：

[1] Univ Trento, Dept Ind Engn, Via Sommar 9, I-38123 Trento, Italy

来源：

MATERIALS & DESIGN | 2017年 / 116卷

关键词：

Replica method; Polyurethane foam; Polymer-derived ceramics; Silicon carbide foam; ELECTRICAL-CONDUCTIVITY; CERAMICS; STRENGTH; FIBER; POLYURETHANE; CARBONITRIDE; LUMINESCENCE; VISCOSITY;

D O I：

10.1016/j.matdes.2016.12.010

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

A method is described here for preparing lightweight and low cost polymer-derived silicon carbide foam by impregnation of preceramic polymer in polyurethane foam. A series of silicon carbide foams with various density (0.035-0.35 g/cm(3)), porosity (87-98%) and thermal conductivity (0.05-0.12 W/m.K) were prepared using allylhydropolycarbosilane as a base material. Surface analysis shows that the resultant foams have an open and interconnected porous structure. Phase analysis shows that it has cubic crystal structure. There was no evidence of cracks or damage even after treating the silicon carbide foam with concentrated hydrofluoric acid for 12 days. From the oxidation resistance experiment, it can be concluded that the silicon carbide foam is stable up to 1500 degrees C in air and 2000 degrees C in argon. (C) 2016 Elsevier Ltd. All rights reserved.

引用

页码：278 / 286

页数：9

共 48 条

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[2]

[Anonymous], 1997, Cellular solid structure and properties

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