A [2]catenane containing an upper-rim functionalized calix[4]arene for anion recognition

被引：26
作者：
Phipps, Dale E. [1 ]
Beer, Paul D. [1 ]
机构：
[1] Univ Oxford, Dept Chem, Chem Res Lab, Oxford OX1 3TA, England
来源：
TETRAHEDRON LETTERS | 2009年 / 50卷 / 26期
基金：
英国工程与自然科学研究理事会;
关键词：
Catenane; Calixarene; Anion recognition; Supramolecular chemistry; CATENANES; ROTAXANES; CONFORMATION; TEMPLATION; MACHINES; FOURFOLD; DEVICES;
D O I：
10.1016/j.tetlet.2009.02.212
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A novel [2]catenane is synthesized in good yield from an upper-rim functionalized calix[4]arene macro-bicycle and a nitro-substituted isophthalamide threading component in the presence of a chloride anion template via a ring-closing metathesis (RCM) reaction. After halide anion template removal the resulting catenane host exhibits a high degree of selectivity for chloride in competitive organic solvent mixtures. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：3454 / 3457
页数：4
相关论文
共 38 条
  • [1] Arduini A, 2000, ANGEW CHEM INT EDIT, V39, P3453, DOI 10.1002/1521-3773(20001002)39:19<3453::AID-ANIE3453>3.0.CO
  • [2] 2-I
  • [3] Selective synthesis of two constitutionally isomeric oriented calix[6]arene-based rotaxanes
    Arduini, A
    Ciesa, F
    Fragassi, M
    Pochini, A
    Secchi, A
    [J]. ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2005, 44 (02) : 278 - 281
  • [4] Unidirectional threading of triphenylureidocalix[6]arene-based wheels: Oriented pseudorotaxane synthesis
    Arduini, A
    Calzavacca, F
    Pochini, A
    Secchi, A
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2003, 9 (03) : 793 - 799
  • [5] DIRECT REGIOSELECTIVE FORMYLATION OF TETRAALKOXYCALIX[4]ARENES FIXED IN THE CONE CONFORMATION AND SYNTHESIS OF NEW CAVITANDS
    ARDUINI, A
    FANNI, S
    MANFREDI, G
    POCHINI, A
    UNGARO, R
    SICURI, AR
    UGOZZOLI, F
    [J]. JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (05) : 1448 - 1453
  • [6] Balzani V, 2002, CHEM-EUR J, V8, P5524, DOI 10.1002/1521-3765(20021216)8:24<5524::AID-CHEM5524>3.0.CO
  • [7] 2-J
  • [8] Anion templated surface assembly of a redox-active sensory rotaxane
    Bayly, Simon R.
    Gray, Thomas M.
    Chmielewski, Michal J.
    Davis, Jason J.
    Beer, Paul D.
    [J]. CHEMICAL COMMUNICATIONS, 2007, (22) : 2234 - 2236
  • [9] Anion-templated assembly of interpenetrated and interlocked structures
    Beer, Paul D.
    Sambrook, Mark R.
    Curiel, David
    [J]. CHEMICAL COMMUNICATIONS, 2006, (20) : 2105 - 2117
  • [10] Rational synthesis of multicyclic bis[2]catenanes
    Bogdan, A
    Vysotsky, MO
    Ikai, T
    Okamoto, Y
    Böhmer, V
    [J]. CHEMISTRY-A EUROPEAN JOURNAL, 2004, 10 (13) : 3324 - 3330
1234