Synthesis and description of the first helical chain of Cu-Pb bimetallic atoms and Cu(I)-Cu(II) mixed-valence

被引：15
|
作者：
Luo, Feng [1 ]
Che, Yun-xia [1 ]
Zheng, Ji-min [1 ]
机构：
[1] Nankai Univ, Dept Chem, Tianjin 300071, Peoples R China
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2006年 / 9卷 / 08期
基金：
中国国家自然科学基金;
关键词：
hydrothermal synthesis; Helical chain; ip; obpy; molecular recognization; 4,4 '-bpy;
D O I：
10.1016/j.inoche.2006.03.010
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
An unprecedented Cu(I)/Cu(II)/Pb(II)-containing coordination polymer, {Pb(ip)(2)[Cu-2(II)(obpy)(2)][Cu-2(I)(obpy)(2)]}(n)(H2O)(2n) 1(ip = isophthalate, Hobpy = 6-hydroxy-2,2-bipyridine), which comprises two single-stranded helical chains recognizing each other to generate molecular zipper structure and parallel double-stranded helices under the direction of supramolecular interaction, is synthesized hydrothermally and characterized by IR, ICP, TG-DTA, and so on. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码：848 / 851
页数：4
相关论文
共 50 条
  • [1] DEFORMATIONS IN MIXED-VALENCE CU(I)-CU(II) POLYMERS
    SHERWOOD, P
    HOFFMANN, R
    INORGANIC CHEMISTRY, 1989, 28 (03) : 509 - 518
  • [2] Synthesis and Characterization of Cu(II) and Mixed-Valence Cu(I)Cu(II) Clusters Supported by Pyridylamide Ligands
    Schneider, Joseph D.
    Smith, Brett A.
    Williams, Grant A.
    Powell, Douglas R.
    Perez, Felio
    Rowe, Gerard T.
    Yang, Lei
    INORGANIC CHEMISTRY, 2020, 59 (08) : 5433 - 5446
  • [3] An unusual mixed-valence Cu(I)-Cu(II) 3-D framework
    Zhao, H
    Qu, ZR
    Ye, Q
    Wang, XS
    Zhang, J
    Xiong, RG
    You, XZ
    INORGANIC CHEMISTRY, 2004, 43 (06) : 1813 - 1815
  • [4] MIXED-VALENCE CU(I)CU(II) MACROCYCLIC COMPLEX - A RESULT OF A CU(II)-PROMOTED OXIDATION OF AZIRIDINES INTO CYANIDE
    AGNUS, Y
    GISSELBRECHT, JP
    LOUIS, R
    METZ, B
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1989, 111 (04) : 1494 - 1496
  • [5] SPECTROSCOPIC PROPERTIES AND CATALYTIC ACTIVITY OF A HOMOBINUCLEAR CU(II)CU(I) MIXED-VALENCE COMPLEX
    LAPINTE, C
    MEYER, G
    NADJO, L
    RIVIERE, H
    NOUVEAU JOURNAL DE CHIMIE-NEW JOURNAL OF CHEMISTRY, 1984, 8 (03): : 165 - 169
  • [6] Thermodynamic description of the Cu-Pb-Sn system at the Cu-Pb side
    Miettinen, J.
    Docheva, P.
    Vassilev, G.
    CALPHAD-COMPUTER COUPLING OF PHASE DIAGRAMS AND THERMOCHEMISTRY, 2010, 34 (04): : 415 - 420
  • [7] DETECTION OF TRANSIENT CU-I-CU-I-CU-II MIXED-VALENCE ACETYLIDE COMPLEXES FROM NANOSECOND TRANSIENT ABSORPTION STUDIES
    YAM, VWW
    LEE, WK
    YEUNG, PKY
    PHILLIPS, D
    JOURNAL OF PHYSICAL CHEMISTRY, 1994, 98 (31): : 7545 - 7547
  • [8] From Cu(i) and Cu(i)-Cu(ii) mixed-valence clusters to 2D Cu(ii) and Cu(i) coordination polymers supported by a flexible bis-tetrazole organosulfur ligand
    Gomez-Paz, Olaya
    Carballo, Rosa
    Lago, Ana B.
    Prieto, Inmaculada
    Vazquez-Lopez, Ezequiel M.
    DALTON TRANSACTIONS, 2023, 52 (31) : 10975 - 10986
  • [9] Cu(I)Cu(II)BTC, a microporous mixed-valence MOF via reduction of HKUST-1
    Ahmed, Adham
    Robertson, Craig M.
    Steiner, Alexander
    Whittles, Thomas
    Ho, Alexandra
    Dhanak, Vinod
    Zhang, Haifei
    RSC ADVANCES, 2016, 6 (11): : 8902 - 8905
  • [10] Cu(I)/Cu(II) Creutz-Taube Mixed-Valence 2D Coordination Polymers
    Li, Ning
    Wu, Gang
    Xi, Shibo
    Wei, Fengxia
    Lin, Ming
    Qiu, Jinjun
    Zheng, Jin-Cheng
    Yi, Jiabao
    Seng, Debbie Hwee Leng
    Lee, Coryl Jing Jun
    Repaka, D. V. Maheswar
    Liu, Xiaoming
    Wong, Zicong Marvin
    Zhu, Qiang
    Yang, Shuo-Wang
    Luo, He-Kuan
    SMALL METHODS, 2023, 7 (01)
12345