Selective interactions of trivalent cations Fe3+ Al3+ and Cr3+ turn on fluorescence in a naphthalimide based single molecular probe

被引：40

作者：

Janakipriya, Subramaniyan ^{[1
]}

Chereddy, Narendra Reddy ^{[2
]}

Korrapati, Purnasai ^{[3
]}

Thennarasu, Sathiah ^{[1
]}

Mandal, Asit Baran ^{[4
]}

机构：

[1] CSIR Cent Leather Res Inst, Organ Chem Lab, Madras 600020, Tamil Nadu, India

[2] CSIR Indian Inst Chem Technol, Crop Protect Chem Div, Hyderabad 500007, Andhra Pradesh, India

[3] CSIR Cent Leather Res Inst, Biomat Lab, Madras 600020, Tamil Nadu, India

[4] CSIR Cent Leather Res Inst, Chem Lab, Madras 600020, Tamil Nadu, India

来源：

SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY | 2016年 / 153卷

关键词：

Naphthalimide derivative; PET inhibition; Fluorescence turn-on; Trivalent cations; Live cell imaging; ALZHEIMERS-DISEASE; ALUMINUM; IONS; FLUOROPHORE; MECHANISMS; STRATEGIES; CHROMIUM; WATER;

D O I：

10.1016/j.saa.2015.08.044

中图分类号：

O433 [光谱学];

学科分类号：

0703 ; 070302 ;

摘要：

Synthesis and fluorescence turn-on behavior of a naphthalimide based probe is described. Selective interactions of trivalent cations Fe3+, Al3+ or Cr3+ with probe 1 inhibit the PET operating in the probe, and thereby, permit the detection of these trivalent cations present in aqueous samples and live cells. Failure of other trivalent cations (Eu3+, Gd3+ and Nb3+) to inhibit the PET process in 1 demonstrates the role of chelating ring size vis-a-vis ionic radius in the selective recognition of specific metal ions. (C) 2015 Elsevier B.V. All rights reserved.

引用

页码：465 / 470

页数：6

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