Non-isothermal kinetics of free-radical polymerization of 2,2-dinitro-1-butyl acrylate

被引：1

作者：

Du, S. H. ^{[1
]}

Zhang, G. Z. ^{[1
]}

Li, H. H. ^{[1
]}

Wang, P. ^{[1
]}

Wang, X. C. ^{[2
]}

机构：

[1] Beijing Inst Technol, Sch Chem Engn & Environm, Beijing 100081, Peoples R China

[2] China Acad Engn Phys, Inst Chem Mat, Mianyang 621900, Peoples R China

来源：

JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 2009年 / 95卷 / 02期

关键词：

2,2-dinitro-1-butyl acrylate; DSC; free-radical polymerization; kinetics; THERMOGRAVIMETRIC DATA; METHACRYLATES; CRYSTALLIZATION;

D O I：

10.1007/s10973-008-9253-2

中图分类号：

O414.1 [热力学];

学科分类号：

摘要：

The free-radical bulk polymerization of 2,2-dinitro-1-butyl-acrylate (DNBA) in the presence of 2,2'-azobisisobutyronitrile (AIBN) as the initiator was investigated by DSC in the non-isothermal mode. Kissinger and Ozawa methods were applied to determine the activation energy (E (a)) and the reaction order of free-radical polymerization. The results showed that the temperature of exothermic polymerization peaks increased with increasing the heating rate. The reaction order of non-isothermal polymerization of DNBA in the presence of AIBN is approximately 1. The average activation energy (92.91 +/- 1.88 kJ mol (-1)) obtained was smaller slightly than the value of E (a)=96.82 kJ mol(-1) found with the Barrett method.

引用

页码：427 / 431

页数：5

共 20 条

[1] Non-isothermal kinetics of free-radical polymerization of 2,2-dinitro-1-butyl acrylate
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H. H. Li
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X. C. Wang
Journal of Thermal Analysis and Calorimetry, 2009, 95 : 427 - 431
[2] Nonisothermal Kinetics of Free-Radical Polymerization of 2,2-Dinitropropyl Methacrylate
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[3] Kinetics of Bulk Free-Radical Polymerization of Butyl Methacrylate Isomers Studied by Reaction Calorimetry\
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[5] Role of Functional Groups in the Monomer Molecule on the Radical Polymerization in the Presence of Graphene Oxide. Polymerization of Hydroxyethyl Acrylate under Isothermal and Non-Isothermal Conditions
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[7] Bulk Free-Radical Co- and Terpolymerization of n-Butyl Acrylate/2-Ethylhexyl Acrylate/Methyl Methacrylate
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[8] MACROTHIURAM DISULFIDE FOR THE FREE-RADICAL SYNTHESIS OF PDMS VINYL TRIBLOCK COPOLYMERS .1. SYNTHESES AND POLYMERIZATION KINETICS
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[9] Poly (Butyl Acrylate)-Graft-Polystyrene Synthesis by Free-Radical Polymerization: Interplay between Structure, Morphology, Mechanical, and Optical Properties
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[10] Influence of butyl group of tin chloride initiators on the non-isothermal DSC ring-opening polymerization of ε-caprolactone: The studies of kinetics, mechanism and polymer synthesis
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