A fluctuation theory analysis of the salting-out effect

被引：10
|
作者：
Mazo, Robert M. [1 ]
机构：
[1] Univ Oregon, Inst Theoret Sci, Eugene, OR 97403 USA
[2] Univ Oregon, Dept Chem, Eugene, OR 97403 USA
来源：
JOURNAL OF PHYSICAL CHEMISTRY B | 2006年 / 110卷 / 47期
关键词：
D O I：
10.1021/jp0656936
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
An analysis of the salting-out, or Sechenow, effect is given in terms of Kirkwood-Buff, or fluctuation, integrals. The analysis is formally exact but cannot easily be applied in its original form. When the solute that is being salted out is sparingly soluble, simplifications arise and the theory can be used to compute one of the Kirkwood-Buff integrals which is otherwise difficult to obtain.
引用
收藏
页码：24077 / 24082
页数：6
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