Highly efficient and reversible iodine capture using a metalloporphyrin-based conjugated microporous polymer

被引：216

作者：

Sigen, A. ^{[1
]}

Zhang, Yuwei ^{[1
]}

Li, Zhongping ^{[1
]}

Xia, Hong ^{[2
]}

Xue, Ming ^{[3
]}

Liu, Xiaoming ^{[1
]}

Mu, Ying ^{[1
]}

机构：

[1] Jilin Univ, Coll Chem, State Key Lab Supramol Struct & Mat, Changchun 130012, Peoples R China

[2] Jilin Univ, Coll Elect Sci & Technol, State Key Lab Integrated Optoelect, Changchun 130012, Peoples R China

[3] Jilin Univ, Coll Chem, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China

来源：

CHEMICAL COMMUNICATIONS | 2014年 / 50卷 / 62期

基金：

中国国家自然科学基金;

关键词：

COVALENT ORGANIC FRAMEWORKS; ELECTRICAL-CONDUCTIVITY; RADIOACTIVE IODINE; VOLATILE IODINE; SINGLE-CRYSTAL; RELEASE; ADSORPTION; PIMS;

D O I：

10.1039/c4cc01783h

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new metalloporphyrin-based conjugated microporous polymer, NiP-CMP, was constructed via a homo-coupling polymerization reaction. NiP-CMP possesses a high BET surface area of over 2600 m(2) g(-1), a large pore volume of 2.288 cm(3) g(-1), good stability, and displays excellent guest uptake of 202 wt% in iodine vapour. We also highlight that the polymer exhibits outstanding performance for the reversible adsorption of iodine in solution.

引用

页码：8495 / 8498

页数：4

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