Solar photocatalytic degradation of real textile effluents by associated titanium dioxide and hydrogen peroxide

被引:44
作者
Garcia, Juliana Carla [1 ]
Simionato, Julliana Isabelle [1 ]
Eugenio, Alessandra [1 ]
da Silva, Carli [1 ]
Nozaki, Jorge [1 ]
de Souza, Nilson Evelazio [1 ]
机构
[1] Univ Estadual Maringa, Dept Chem, BR-87020900 Maringa, Parana, Brazil
关键词
Textile effluents; Titanium dioxide; Hydrogen peroxide; Mineralization; AQUEOUS SUSPENSION; OXIDATION; TIO2; PHOTODEGRADATION; MINERALIZATION; WATER;
D O I
10.1016/j.solener.2008.08.004
中图分类号
TE [石油、天然气工业]; TK [能源与动力工程];
学科分类号
0807 ; 0820 ;
摘要
The present work investigated the photodegradation of real textile effluents by advanced oxidative process (AOP) using TiO2/H2O2/ sunlight system. The procedures were carried out at ambient conditions in March 2005. The results were evaluated by COD reduction concomitant to the increase in inorganic ion concentration (mineralization) and the analysis of the effluent characteristic spectral wavelengths: 228, 254, and 284 nm (simple aromatic compounds), 3 10 nm (conjugated aromatic compounds), and 390, 450, and 530 (color). As this study is not restricted to the decolorization process, it allows a more reliable evaluation of effluent mineralization. The results indicate that solar radiation is as efficient as or even more efficient than artificial radiation was in previous studies and that it also allows a reduction in effluent treatment operational costs. (c) 2008 Elsevier Ltd. All rights reserved.
引用
收藏
页码:316 / 322
页数:7
相关论文
共 23 条
[1]  
APHA/AWWA/WEF, 2017, Standard Methods for the Examination of Water and Wastewater, V23rd
[2]   Photocatalytic oxidation of cyanide in aqueous TiO2 suspensions irradiated by sunlight in mild and strong oxidant conditions [J].
Augugliaro, V ;
Gálvez, JB ;
Vázquez, JC ;
López, EG ;
Loddo, V ;
Muñoz, MJL ;
Rodríguez, SM ;
Marcì, G ;
Palmisano, L ;
Schiavello, M ;
Ruiz, JS .
CATALYSIS TODAY, 1999, 54 (2-3) :245-253
[3]   Photocatalytic oxidation of acetonitrile in aqueous suspension of titanium dioxide irradiated by sunlight [J].
Augugliaro, V ;
Prevot, AB ;
Vázquez, JC ;
García-López, E ;
Irico, A ;
Loddo, V ;
Rodríguez, SM ;
Marcì, G ;
Palmisano, L ;
Pramauro, E .
ADVANCES IN ENVIRONMENTAL RESEARCH, 2004, 8 (3-4) :329-335
[4]   Comparison of various advanced oxidation processes and chemical treatment methods for COD and color removal from a polyester and acetate fiber dyeing effluent [J].
Azbar, N ;
Yonar, T ;
Kestioglu, K .
CHEMOSPHERE, 2004, 55 (01) :35-43
[5]   Application of photocatalytic oxidation treatment to pretreated and raw effluents from the Kraft bleaching process and textile industry [J].
Balcioglu, IA ;
Arslan, I .
ENVIRONMENTAL POLLUTION, 1998, 103 (2-3) :261-268
[6]   Role of primary active species and TiO2 surface characteristic in UV-illuminated photodegradation of Acid Orange 7 [J].
Chen, YX ;
Yang, SY ;
Wang, K ;
Lou, LP .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2005, 172 (01) :47-54
[7]   Photooxidation of the phenylazonaphthol AO20 on TIO2:: kinetic and mechanistic investigations [J].
Galindo, C ;
Jacques, P ;
Kalt, A .
CHEMOSPHERE, 2001, 45 (6-7) :997-1005
[8]   Comparative study of the degradation of real textile effluents by photocatalytic reactions involving UV/TiO2/H2O2and UV/Fe2+/H2O2 systems [J].
Garcia, J. C. ;
Oliveira, U. ;
Silva, A. E. C. ;
Oliveira, C. C. ;
Nozaki, J. ;
de Souza, N. E. .
JOURNAL OF HAZARDOUS MATERIALS, 2007, 147 (1-2) :105-110
[9]   Photocatalytic degradation of imazaquin in an aqueous suspension of titanium dioxide [J].
Garcia, JC ;
Takashima, K .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 2003, 155 (1-3) :215-222
[10]   PHOTODEGRADATION OF SURFACTANTS .14. FORMATION OF NH4+ AND NO3- IONS FOR THE PHOTOCATALYZED MINERALIZATION OF NITROGEN-CONTAINING CATIONIC, NONIONIC AND AMPHOTERIC SURFACTANTS [J].
HIDAKA, H ;
NOHARA, K ;
ZHAO, JC ;
PELIZZETTI, E ;
SERPONE, N .
JOURNAL OF PHOTOCHEMISTRY AND PHOTOBIOLOGY A-CHEMISTRY, 1995, 91 (02) :145-152