New indole-containing luminophores: convenient synthesis and aggregation-induced emission enhancement

被引：29

作者：

Li, Qianqian ^{[1
]}

Yu, Shanshan ^{[1
]}

Li, Zhen ^{[1
]}

Qin, Jingui ^{[1
]}

机构：

[1] Wuhan Univ, Dept Chem, Hubei Key Lab Organ & Polymer Optoelect Mat, Wuhan 430072, Peoples R China

来源：

JOURNAL OF PHYSICAL ORGANIC CHEMISTRY | 2009年 / 22卷 / 03期

基金：

美国国家科学基金会;

关键词：

indole; aggregation-induced emission enhancement; carbon-nitrogen bonds; LIGHT-EMITTING-DIODES; MAIN-CHAIN POLYURETHANES; SOLID-STATE; OPTICAL-PROPERTIES; SITE-ISOLATION; FLUORESCENCE; PHOTOLUMINESCENCE; FLUOROPHORES; LUMINESCENCE; CHROMOPHORES;

D O I：

10.1002/poc.1461

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A series of new indole-based luminophores (IIa-d) were conveniently synthesized through Ullmann reactions. They were well characterized by spectroscopic analyses and exhibited aggregation-induced emission enhancement (AIEE) properties. By simply changing the aromatic moieties in IIa-d, their maximum emission wavelengths could be well-tuned from 340 to 400 nm. The obtained experimental results, including the fluorescent behavior and the crystal structure in solid, demonstrated that the AIEE phenomena are caused by the restrictions of the intramolecular indolyl vibrational and rotational motions (around the Carbon-Nitrogen bonds). Copyright (C) 2008 John Wiley & Sons, Ltd.

引用

页码：241 / 246

页数：6

共 73 条

[1] The synthesis and properties of carbazole-phenylazomethine double layer-type dendrimers [J].

Albrecht, Ken ;

Kasai, Yuto ;

Kimoto, Atsushi ;

Yamamoto, Kimihisa .

MACROMOLECULES, 2008, 41 (11) :3793-3800

[2] Enhanced emission and its switching in fluorescent organic nanoparticles [J].

An, BK ;

Kwon, SK ;

Jung, SD ;

Park, SY .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (48) :14410-14415

[3] A highly potassium-selective ratiometric fluorescent indicator based on BODIPY azacrown ether excitable with visible light [J].

Baruah, M ;

Qin, WW ;

Vallée, RAL ;

Beljonne, D ;

Rohand, T ;

Dehaen, W ;

Boens, N .

ORGANIC LETTERS, 2005, 7 (20) :4377-4380

[4] Excited-state quenching of a highly luminescent conjugated polymer [J].

Belton, C ;

O'Brien, DF ;

Blau, WJ ;

Cadby, AJ ;

Lane, PA ;

Bradley, DDC ;

Byrne, HJ ;

Stockmann, R ;

Hörhold, HH .

APPLIED PHYSICS LETTERS, 2001, 78 (08) :1059-1061

[5] Relaxation dynamics and structural characterization of organic nanoparticles with enhanced emission [J].

Bhongale, CJ ;

Chang, CW ;

Lee, CS ;

Diau, EWG ;

Hsu, CS .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (28) :13472-13482

[6] Emission enhancement by formation of aggregates in hybrid chromophoric surfactant amphiphile/silica nanocomposites [J].

Bhongale, CJ ;

Hsu, CS .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2006, 45 (09) :1404-1408

[7] Charge-mediated recognition of N-terminal tryptophan in aqueous solution by a synthetic host [J].

Bush, ME ;

Bouley, ND ;

Urbach, AR .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2005, 127 (41) :14511-14517

[8] Synthesis and functionalization of Indoles through palladium-catalyzed reactions [J].

Cacchi, S ;

Fabrizi, G .

CHEMICAL REVIEWS, 2005, 105 (07) :2873-2920

[9] Optimization of high-performance blue organic light-emitting diodes containing tetraphenylsilane molecular glass materials [J].

Chan, LH ;

Lee, RH ;

Hsieh, CF ;

Yeh, HC ;

Chen, CT .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2002, 124 (22) :6469-6479

[10] Ortho-substituent effect on fluorescence and electroluminescence of arylamino-substituted coumarin and stilbene [J].

Chen, CT ;

Chiang, CL ;

Lin, YC ;

Chan, LH ;

Huang, CH ;

Tsai, ZW ;

Chen, CT .

ORGANIC LETTERS, 2003, 5 (08) :1261-1264

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