{[Ag2 (-dppm)2 (-TCNQ)2](TCNQ)}, a charge transfer compound derived from a donor with a metal-metal bond

被引：3
作者：
Lv, Qi-Ying [1 ]
Song, Yong-Qin [1 ]
Zhan, Shu-Zhong [1 ]
Cai, Jian [1 ]
He, Jian-Ping [1 ]
机构：
[1] S China Univ Technol, Dept Chem, Guangzhou, Guangdong, Peoples R China
来源：
JOURNAL OF COORDINATION CHEMISTRY | 2009年 / 62卷 / 09期
关键词：
Silver dimer; Charge transfer; Luminescence; HIGH ELECTRICAL-CONDUCTIVITY; CRYSTAL-STRUCTURE; MAGNETIC-PROPERTIES; STRUCTURAL-CHARACTERIZATION; SILVER(I) COMPLEXES; TCNQ; LIGANDS; 7,7,8,8-TETRACYANOQUINODIMETHANE; SYSTEMS; DESIGN;
D O I：
10.1080/00958970802644969
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Reaction of AgNO3, dppm (bis(diphenylphosphino)methane), and TCNQ in molar ratio of 1 : 1 : 1 produced an acceptor-donor silver compound {[Ag2(dppm)2 (-TCNQ)2](TCNQ)}, 1. In the structure, determined by X-ray crystallography, two silver atoms are triply-bridged by two dppm ligands and metal-metal bond to form a dimer; the distance between two Ag is 3.1753(8) . Compound 1 was studied by IR and UV/Vis/NIR spectroscopy, exhibiting an intervalence transfer transition at = 1286 nm, and also is photoluminescent (max = 537 and 654 nm) at room temperature.
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页码：1536 / 1543
页数：8
相关论文
共 39 条
[1]   SYNTHESIS AND CRYSTAL-STRUCTURE OF A METHYLENEBIS(DI-PHENYLPHOSPHANE) COMPLEX OF SILVER BROMIDE CONTAINING A TRIGONAL BIPYRAMIDAL AG3BR2 CENTRAL UNIT [J].
ALY, AAM ;
NEUGEBAUER, D ;
ORAMA, O ;
SCHUBERT, U ;
SCHMIDBAUR, H .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1978, 17 (02) :125-126
[2]   A RADICAL-ANION SALT OF 2,5-DIMETHYL-N,N'-DICYANOQUINONEDIIMINE WITH EXTREMELY HIGH ELECTRICAL-CONDUCTIVITY [J].
AUMULLER, A ;
ERK, P ;
KLEBE, G ;
HUNIG, S ;
VONSCHUTZ, JU ;
WERNER, HP .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1986, 25 (08) :740-741
[3]   A NEW CLASS OF COMPOUNDS WITH HIGH ELECTRICAL-CONDUCTIVITY [J].
AUMULLER, A ;
ERK, P ;
HUNIG, S ;
VONSCHUTZ, JU ;
WERNER, HP ;
WOLF, HC ;
KLEBE, G .
MOLECULAR CRYSTALS AND LIQUID CRYSTALS, 1988, 156 :215-221
[4]   MULTISTEP REDOX SYSTEMS .55. CRYSTAL-STRUCTURE OF THE CT-COMPLEX 2,5-ME2-DCNQI TTF FROM N,N'-DICYANO-2,5-DIMETHYL-1,4-BENZOQUINONE DIIMINE AND TETRATHIAFULVALENE AND OF THE ACCEPTOR 2,5-ME2-DCNQI [J].
AUMULLER, A ;
ERK, P ;
HUNIG, S ;
HADICKE, E ;
PETERS, K ;
VONSCHNERING, HG .
CHEMISCHE BERICHTE, 1991, 124 (09) :2001-2004
[5]   [(RE2CL4(DPPM)2)2(MU-TCNQ)], A NOVEL CHARGE-TRANSFER COMPLEX DERIVED FROM A DONOR WITH A METAL-METAL MULTIPLE BOND [J].
BARTLEY, SL ;
DUNBAR, KR .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1991, 30 (04) :448-450
[6]   Tetranuclear osmium complexes of tetracyanoquinodimethane [TCNQ, 2,2'-(cyclohexa-2,5-diene-1,4-diylidene)bis(propane-1,3-dinitrile)] and 1,2,4,5-tetracyanobenzene (TCNB). Synthesis, spectroelectrochemistry and magnetism [J].
Baumann, F ;
Kaim, W ;
Olabe, JA ;
Parise, AR ;
Jordanov, J .
JOURNAL OF THE CHEMICAL SOCIETY-DALTON TRANSACTIONS, 1997, (22) :4455-4459
[7]   Spectroscopic evidence for argentophilicity in structurally characterized luminescent binuclear silver(I) complexes [J].
Che, CM ;
Tse, MC ;
Chan, MCW ;
Cheung, KK ;
Phillips, DL ;
Leung, KH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2000, 122 (11) :2464-2468
[8]   TCNE and TCNQ ligands as efficient bridges in mixed-valence complexes containing iron-cyclopentadienyl and other organometallic systems [J].
Diaz, C ;
Arancibia, A .
POLYHEDRON, 2000, 19 (02) :137-145
[9]   BINARY-ALLOYS OF 2,5-DISUBSTITUTED DCNQI RADICAL-ANION SALTS OF COPPER AND THEIR ELECTRICAL-CONDUCTIVITY [J].
ERK, P ;
GROSS, HJ ;
HUNIG, S ;
LANGOHR, U ;
MEIXNER, H ;
WERNER, HP ;
VONSCHUTZ, JU ;
WOLF, HC .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1989, 28 (09) :1245-1246
[10]   ELECTRON DELOCALIZATION IN MOLECULE-BRIDGED POLYMETALLIC SYSTEMS - UNIQUE NEUTRAL COMPLEXES OF TCNE OR TCNQ AND UP TO 4 ORGANOMETALLIC FRAGMENTS (C5R5)(CO)2MN [J].
GROSSLANNERT, R ;
KAIM, W ;
OLBRICHDEUSSNER, B .
INORGANIC CHEMISTRY, 1990, 29 (25) :5046-5053
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