Ambient temperature imidazolium-based ionic liquids with tetrachloronickelate(II) anions

被引：23
|
作者：
Meredith, M. Brett [1 ]
McMillen, C. Heather [1 ]
Goodman, Jonathan T. [1 ]
Hanusa, Timothy P. [1 ]
机构：
[1] Vanderbilt Univ, Dept Chem, Nashville, TN 37235 USA
来源：
POLYHEDRON | 2009年 / 28卷 / 12期
关键词：
Ionic liquid; Nickel; Viscosity; Imidazolium; Thermal stability; ELECTROCHEMISTRY; BEHAVIOR;
D O I：
10.1016/j.poly.2009.04.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Deep blue tetrachloronickelate(II) salts of 1-alkyl-3-methyl imidazolium cations [C(n)mim](+) with intermediate chain lengths (n = 5, 7, 8 and an n = 4/6 mixture) have been prepared from imidazolium chlorides and NiCl2. They are liquid at ambient temperatures (ca. 20 degrees C) and above, and display viscosities and thermal stability comparable to related [BF4](-) compounds. The similarities may reflect the compensating effects of the dinegative charge of the [NiCl4](2-) ion and its larger size. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2355 / 2358
页数：4
相关论文
共 50 条
  • [41] Effect of cation structure of tetraalkylammonium- and imidazolium-based ionic liquids on their conductivity
    Arkhipova, Ekaterina A.
    Ivanov, Anton S.
    Maslakov, Konstantin, I
    Savilov, Serguei, V
    Lunin, Valery V.
    ELECTROCHIMICA ACTA, 2019, 297 : 842 - 849
  • [42] Kinetics of imidazolium-based ionic liquids degradation in aqueous solution by Fenton oxidation
    Dominguez, Carmen M.
    Munoz, Macarena
    Quintanilla, Asuncion
    de Pedro, Zahara M.
    Casas, Jose A.
    ENVIRONMENTAL SCIENCE AND POLLUTION RESEARCH, 2018, 25 (35) : 34811 - 34817
  • [43] Vibrational spectroscopy of imidazolium-based ionic liquids: A combined MD/DFT study
    Liu, Jiannan
    Kim, Hyunjin
    Dhumal, Nilesh R.
    Kim, Hyung J.
    JOURNAL OF MOLECULAR LIQUIDS, 2019, 292
  • [44] Decomposition of Imidazolium-Based Ionic Liquids in Contact with Lithium Metal
    Schmitz, Paulo
    Jakelski, Rene
    Pyschik, Marcelina
    Jalkanen, Kirsi
    Nowak, Sascha
    Winter, Martin
    Bieker, Peter
    CHEMSUSCHEM, 2017, 10 (05) : 876 - 883
  • [45] Optimization of cation structure of imidazolium-based ionic liquids as ionic solvents for rechargeable magnesium batteries
    Kakibe, Takeshi
    Yoshimoto, Nobuko
    Egashira, Minato
    Morita, Masayuki
    ELECTROCHEMISTRY COMMUNICATIONS, 2010, 12 (11) : 1630 - 1633
  • [46] Molecular dynamics simulation of imidazolium-based ionic liquids. II. Transport coefficients
    Kowsari, M. H.
    Alavi, Saman
    Ashrafizaadeh, Mahmud
    Najafi, Bijan
    JOURNAL OF CHEMICAL PHYSICS, 2009, 130 (01)
  • [47] The selectivity of imidazolium-based ionic liquids with different anions to BTX aromatics in hexane at 298.15 K and atmospheric pressure
    Lee, Kyeong-Ho
    You, Soo-Hyun
    Park, So-Jin
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2016, 33 (10) : 2982 - 2989
  • [48] Microwave-Assisted Synthesis of Some Potential Bioactive Imidazolium-Based Room-Temperature Ionic Liquids
    Albalawi, Ahmed H.
    El-Sayed, Wael S.
    Aljuhani, Ateyatallah
    Almutairi, Saud M.
    Rezki, Nadjet
    Aouad, Mohamed R.
    Messali, Mouslim
    MOLECULES, 2018, 23 (07):
  • [49] Fluoride ion yield and absorption spectral analysis of irradiated imidazolium-based room-temperature ionic liquids
    Huang, Wei
    Chen, Shimou
    Liu, Yusheng
    Fu, Haiying
    Wu, Guozhong
    RADIATION PHYSICS AND CHEMISTRY, 2011, 80 (04) : 573 - 577
  • [50] The selectivity of imidazolium-based ionic liquids with different anions to BTX aromatics in hexane at 298.15 K and atmospheric pressure
    Kyeong-Ho Lee
    Soo-Hyun You
    So-Jin Park
    Korean Journal of Chemical Engineering, 2016, 33 : 2982 - 2989
12345