Ambient temperature imidazolium-based ionic liquids with tetrachloronickelate(II) anions

被引：23
|
作者：
Meredith, M. Brett [1 ]
McMillen, C. Heather [1 ]
Goodman, Jonathan T. [1 ]
Hanusa, Timothy P. [1 ]
机构：
[1] Vanderbilt Univ, Dept Chem, Nashville, TN 37235 USA
来源：
POLYHEDRON | 2009年 / 28卷 / 12期
关键词：
Ionic liquid; Nickel; Viscosity; Imidazolium; Thermal stability; ELECTROCHEMISTRY; BEHAVIOR;
D O I：
10.1016/j.poly.2009.04.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Deep blue tetrachloronickelate(II) salts of 1-alkyl-3-methyl imidazolium cations [C(n)mim](+) with intermediate chain lengths (n = 5, 7, 8 and an n = 4/6 mixture) have been prepared from imidazolium chlorides and NiCl2. They are liquid at ambient temperatures (ca. 20 degrees C) and above, and display viscosities and thermal stability comparable to related [BF4](-) compounds. The similarities may reflect the compensating effects of the dinegative charge of the [NiCl4](2-) ion and its larger size. (C) 2009 Elsevier Ltd. All rights reserved.
引用
收藏
页码：2355 / 2358
页数：4
相关论文
共 50 条
  • [21] Mesomorphism of imidazolium-based fluorinated ionic liquids
    Pulukkody R.
    Lee Y.J.
    Ware T.H.
    Pentzer E.B.
    Journal of Ionic Liquids, 2024, 4 (01):
  • [22] Modulation of Insulin Amyloid Fibrillization in Imidazolium-Based Ionic Liquids with Hofmeister Series Anions
    Vanik, Vladimir
    Bednarikova, Zuzana
    Fabriciova, Gabriela
    Wang, Steven S. -S.
    Gazova, Zuzana
    Fedunova, Diana
    INTERNATIONAL JOURNAL OF MOLECULAR SCIENCES, 2023, 24 (11)
  • [23] α-chymotrypsin catalysis in imidazolium-based ionic liquids
    Laszlo, JA
    Compton, DL
    BIOTECHNOLOGY AND BIOENGINEERING, 2001, 75 (02) : 181 - 186
  • [24] Thermal stability of imidazolium-based ionic liquids
    Chancelier, Lea
    Boyron, Olivier
    Gutel, Thibaut
    Santini, Catherine C.
    FRENCH-UKRAINIAN JOURNAL OF CHEMISTRY, 2016, 4 (01): : 51 - 64
  • [25] Thermophysical properties of imidazolium-based ionic liquids
    Fredlake, CP
    Crosthwaite, JM
    Hert, DG
    Aki, SNVK
    Brennecke, JF
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2004, 49 (04): : 954 - 964
  • [26] A comparative study of the stability of stem bromelain based on the variation of anions of imidazolium-based ionic liquids
    Kumar, Pannuru Kiran
    Jha, Indrani
    Venkatesu, Pannuru
    Bahadur, Indra
    Ebenso, Eno E.
    JOURNAL OF MOLECULAR LIQUIDS, 2017, 246 : 178 - 186
  • [27] Transport Properties and Ionic Association in Pure Imidazolium-Based Ionic Liquids as a Function of Temperature
    Tsamba, B. E. Mbondo
    Sarraute, S.
    Traikia, M.
    Husson, P.
    JOURNAL OF CHEMICAL AND ENGINEERING DATA, 2014, 59 (06): : 1747 - 1754
  • [28] BIOnic liquids: Imidazolium-based ionic liquids with antimicrobial activity
    1600, Verlag der Zeitschrift fur Naturforschung (68):
  • [29] BIOnic Liquids: Imidazolium-based Ionic Liquids with Antimicrobial Activity
    Postleb, Frank
    Stefanik, Danuta
    Seifert, Harald
    Giernoth, Ralf
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 2013, 68 (10): : 1123 - 1128
  • [30] Imidazolium-based protic ionic liquids with perfluorinated anions: Influence of chemical structure on thermal properties
    Prykhodko, Y.
    Martin, A.
    Oulyadi, H.
    Kobzar, Ya L.
    Marais, S.
    Fatyeyeva, K.
    JOURNAL OF MOLECULAR LIQUIDS, 2022, 345
12345