Singlet and Triplet Exciton Harvesting in the Thin Films of Colloidal Quantum Dots Interfacing Phosphorescent Small Organic Molecules

被引：12

作者：

Guzelturk, Burak ^{[1
,2
]}

Martinez, Pedro Ludwig Hernandez ^{[1
,2
]}

Zhao, Dewei ^{[2
]}

Sun, Xiao Wei ^{[2
]}

Demir, Hilmi Volkan ^{[1
,2
]}

机构：

[1] Bilkent Univ, Dept Phys, Dept Elect & Elect Engn, UNAM Inst Mat Sci & Nanotechnol, TR-06800 Ankara, Turkey

[2] Nanyang Technol Univ, Sch Elect & Elect Engn, Sch Phys & Mat Sci, Luminous Ctr Excellence Semicond Lighting & Displ, Singapore 639798, Singapore

来源：

JOURNAL OF PHYSICAL CHEMISTRY C | 2014年 / 118卷 / 45期

基金：

欧盟第七框架计划;

关键词：

ENERGY-TRANSFER; EFFICIENCY; DEVICES; DISPLAYS; EMISSION;

D O I：

10.1021/jp509799r

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Efficient nonradiative energy transfer is reported in an inorganic/organic thin film that consists of a CdSe/ZnS core/shell colloidal quantum dot (QD) layer interfaced with a phosphorescent small organic molecule (FIrpic) codoped fluorescent host (TCTA) layer. The nonradiative energy transfer in these thin films is revealed to have a cascaded energy transfer nature: first from the fluorescent host TCTA to phosphorescent FIrpic and then to QDs. The nonradiative energy transfer in these films enables very efficient singlet and triplet state harvesting by the QDs with a concomitant fluorescence enhancement factor up to 2.5-fold, while overall nonradiative energy transfer efficiency is as high as 95%. The experimental results are successfully supported by the theoretical energy transfer model developed here, which considers exciton diffusion assisted Forster-type near-field dipoledipole coupling within the hybrid films.

引用

页码：25964 / 25969

页数：6

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