Application of Mesoporous Al-MCM-48 Material to the Conversion of Lignin

被引：14

作者：

Lee, Hyung Won ^{[1
]}

Lee, In-Gu ^{[2
]}

Park, Sung Hoon ^{[3
]}

Jeon, Jong-Ki ^{[4
]}

Suh, Dong Jin ^{[5
]}

Jung, Jinho ^{[6
]}

Park, Young-Kwon ^{[1
,7
]}

机构：

[1] Univ Seoul, Grad Sch Energy & Environm Syst Engn, Seoul 130743, South Korea

[2] Korea Inst Energy Res, Taejon 305343, South Korea

[3] Sunchon Natl Univ, Dept Environm Engn, Sunchon 540950, South Korea

[4] Kongju Natl Univ, Dept Chem Engn, Cheonan 330717, South Korea

[5] Korea Inst Sci & Technol, Clean Energy Res Ctr, Seoul 136791, South Korea

[6] Korea Univ, Div Environm Sci & Ecol Engn, Seoul 136713, South Korea

[7] Univ Seoul, Sch Environm Engn, Seoul 130743, South Korea

来源：

JOURNAL OF NANOSCIENCE AND NANOTECHNOLOGY | 2014年 / 14卷 / 04期

基金：

新加坡国家研究基金会;

关键词：

Biomass Component; Lignin; Al-MCM-48; Catalytic Fast Pyrolysis; CATALYTIC FAST PYROLYSIS; BIOETHANOL PRODUCTION; BIODIESEL PRODUCTION; WASTE; FERMENTATION; SELECTIVITY; HYDROLYSIS; AROMATICS; CHEMICALS;

D O I：

10.1166/jnn.2014.8634

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Al-MCM-48 was applied to the catalytic pyrolysis of lignin for the first time. The pyrolysis reaction and in-situ product were analyzed by pyrolysis gas chromatography/mass spectrometry. The main products of the non-catalytic pyrolysis of lignin were phenols. The use of Al-MCM-48 increased the production of light phenols considerably. The yields of high-value-added compounds, such as hydrocarbons and aromatics, were also increased by catalytic upgrading. Al-MCM-48 is believed to promote cracking, aromatization and deoxygenation, such as decarbonylation. On the other hand, Si-MCM-48, which has no acid sites, showed lower deoxygenation efficiency than Al-MCM-48. Al-MCM-48 could be regenerated by calcining in air.

引用

页码：2990 / 2995

页数：6

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