Selective One-Pot Production of High-Grade Diesel-Range Alkanes from Furfural and 2-Methylfuran over Pd/NbOPO4

被引：65

作者：

Xia, Qineng ^{[1
]}

Xia, Yinjiang ^{[1
]}

Xi, Jinxu ^{[1
]}

Liu, Xiaohui ^{[1
]}

Zhang, Yongguang ^{[2
]}

Guo, Yong ^{[2
]}

Wang, Yanqin ^{[1
]}

机构：

[1] East China Univ Sci Technol, Shanghai Key Lab Funct Mat Chem & Res, Inst Ind Catalysis, Sch Chem & Mol Engn, 130,Meilong Rd, Shanghai 200237, Peoples R China

[2] SINOPEC, Res Inst Petr Proc, 18,Xueyuan Rd, Beijing 100083, Peoples R China

来源：

CHEMSUSCHEM | 2017年 / 10卷 / 04期

基金：

中国博士后科学基金; 中国国家自然科学基金;

关键词：

alkanes; alkylation; diesel; furfural; hydrodeoxygenation; HIGH-QUALITY DIESEL; C BOND FORMATION; LIQUID ALKANES; DIRECT HYDRODEOXYGENATION; LIGNOCELLULOSIC BIOMASS; CATALYTIC CONVERSION; RENEWABLE DIESEL; FUEL SYNTHESIS; SOLID ACID; HEMICELLULOSE;

D O I：

10.1002/cssc.201601522

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A one-pot method for the selective production of high-grade diesel-range alkanes from biomass-derived furfural and 2-methylfuran (2-MF) was developed by combining the hydroxyalkylation/alkylation (HAA) condensation of furfural with 2-MF and the subsequent hydrodeoxygenation (HDO) over a multifunctional Pd/NbOPO4 catalyst. The effects of various reaction conditions as well as a variety of solid-acid catalysts and metal-loaded NbOPO4 catalysts were systematically investigated to optimize the reaction conditions for both reactions. Under the optimal reaction conditions up to 89.1% total yield of diesel-range alkanes was obtained from furfural and 2-MF by this one-pot method.

引用

页码：747 / 753

页数：7

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