Electrosyntheses of high quality free-standing poly(9-fluorenone) films in boron trifluoride diethyl etherate

被引：40
作者：
Zhang, Shusheng
Nie, Guangming
Han, Xuejun
Xu, Jingkun
Li, Mingsheng
Cai, Tao
机构：
[1] Qingdao Univ Sci & Technol, Coll Chem & Mol Engn, Qingdao 266042, Peoples R China
[2] Jiangxi Sci & Technol Normal Univ, Jiangxi Key Lab Organ Chem, Nanchang 330013, Peoples R China
来源：
ELECTROCHIMICA ACTA | 2006年 / 51卷 / 26期
基金：
中国国家自然科学基金;
关键词：
electrochemical polymerization; conducting polymer; poly(9-fluorenone); boron trifluoride diethyl etherate; polyfluorene;
D O I：
10.1016/j.electacta.2006.03.010
中图分类号：
O646 [电化学、电解、磁化学];
学科分类号：
081704 ;
摘要：
High quality free-standing poly(9-fluorenone) (PFO) films were synthesized electrochemically by direct anodic oxidation of 9-fluorenone (FO) in pure boron trifluoride diethyl etherate (BFEE). The oxidation potential of FO in this medium was measured to be only 1.48 V versus SCE, which was greatly lower than that determined in CH2Cl2 + 0.1 mol l(-1) Bu4NBF4 (2.21 V versus SCE). PFO films obtained from BFEE showed good electrochemical behavior, good thermal stability with electrical conductivity of 7.8 x 10(-3) S cm(-1), indicating that BFEE was a better medium than CH2Cl2 for the electrosyntheses of PFO films. Structural studies showed that the polymerization of FO ring occurred at 2,7-position. As-formed PFO films can be partly dissolved in acetone and tetrahydrofuran (THF). Fluorescent spectral studies indicate that PFO is a good blue light emitter. To the best of our knowledge, this is the first report on the electrosyntheses of free-standing PFO films. (c) 2006 Elsevier Ltd. All rights reserved.
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收藏
页码：5738 / 5745
页数：8
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