Synthesis and crystal structure of 2-propyl-5-phenyl-1,4-dioxo-1,2,3,4,5,6,7,8-octahydro-[1,4,2]diazaphosphorino[1,2-a][1,3,2]benzodiazaphosphorine 3-oxide

被引：2

作者：

Huang, JM ^{[1
]}

Chen, H

Chen, RY

机构：

[1] Nankai Univ, Inst Elementoorgan Chem, Tianjin 300071, Peoples R China

[2] Procter & Gamble Technol Beijing Co, Beijing, Peoples R China

来源：

JOURNAL OF CHEMICAL CRYSTALLOGRAPHY | 2001年 / 31卷 / 9-10期

基金：

中国国家自然科学基金;

关键词：

crystal structure; 1,4,2]diazaphosphorino[1,2-a][1,3,2]benzodiazaphosphorine;

D O I：

10.1023/A:1015683720074

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

The synthesis and structure characterization of 2-propyl-5-phenyl-1,4-dioxo-1,2,3,4,5, 6,7,8-octahydro-[1,4,2]diazaphosphorino[1,2-a][1,3,2]benzodiazaphosphorine 3-oxide are described. The title compound has been designed to incorporate proximate carbonyl and phosphoryl groups in a heterocycle fused to benzophosphadiamide heterocycle. Crystal data: C(1)9H(2)0N(3)O(3)P, Monoclinic, space group P2(1)/c, with a = 9.7585(9) Angstrom, b = 21.4319(19) Angstrom, c = 17.7900(16) Angstrom, beta = 100.823(2)degrees, Z = 8, V = 3654.5(6) Angstrom(3). The crystal structure shows that the proximate carbonyl and phosphoryl groups are not coplanar, and the [1,4,2]diazaphosphorino moiety prefers the boat conformation.

引用

页码：445 / 452

页数：8

共 50 条

[1] Synthesis and crystal structure of 2-propyl-5-phenyl-1, 4-dioxo-1,2,3,4,5,6,7,8-octahydro-[1,4,2]diazaphosphorino [1,2-a][1,3,2]benzodiazaphosphorine 3-oxide
Junmin Huang
Hui Chen
Ruyu Chen
Journal of Chemical Crystallography, 2001, 31 : 445 - 452
[2] Synthesis and crystal structure of 2-morpholinylthioformyl-2-phenyl-4-morpholinyl-5-phenyl-1, 3-dithiole
Zou, JP
Wang, XS
Zhang, J
Zeng, RS
Lu, ZE
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2000, 19 (06) : 423 - 426
[3] Synthesis and crystal structure of 4-phenyl-7,7-dimethyl-2,5-dioxo-1,2,3,4,5,6,7,8-octahydroquinolin under microwave irradiation
Tu, SJ
Shi, DQ
Yao, CS
Wang, SH
Wang, XS
Wang, YC
Dai, GY
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (01) : 49 - 52
[4] Crystal structure of 2 '-[(2 ',4 '-difluorobipheny1-4yl)carbonyl]-1 '-phenyl-1 ',2 ',5 ',6 ',7 ',7a '-hexahydro- spiro[indole-3 3 '-pyrrolizin]-2(1H)-one
Fathimunnisa, M.
Manikandan, H.
Selvanayagam, S.
Sridhar, B.
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2015, 71 : 915 - +
[5] Synthesis and crystal structure of 2-anilino-6H-5-(1-phenyl-3-methyl-5-pyrazolone-4-ylene)-1,3,4-thiadiazine
Liu, GF
Liu, L
Jia, DZ
Yu, KB
JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 2004, 34 (12) : 835 - 841
[6] Crystal structure of 4-(4-chlorophenyl)-7,7-dimethyl-2,5-dioxo-1,2,3,4,5,6,7,8-octahydroquinoline
Tu, SJ
Zhou, JF
Gao, Y
Liu, XH
CHINESE JOURNAL OF STRUCTURAL CHEMISTRY, 2001, 20 (06) : 459 - 461
[7] Synthesis and crystal structure of 2-ethylamino-6H-5-(1-phenyl-3-methyl/phenyl-5-pyriazolone-4-ylene)-1,3,4-thiadiazine
Peng, BH
Liu, GF
Liu, L
Jia, DZ
Yu, KB
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2004, 25 (12): : 2278 - 2283
[8] Synthesis and crystal structure of 2-anilino-6H-5-(1-phenyl-3-methyl-5-pyrazolone-4-ylene)-1,3,4-thiadiazine
Guang-Fei Liu
Lang Liu
Dian-Zeng Jia
Kai-Bei Yu
Journal of Chemical Crystallography, 2004, 34 : 835 - 841
[9] Crystal Structure of Triethyl 6-benzoyl-3a-(4-fluorophenyl)-2,3,3a,4,5,6-hexahydro-5-methyl-1H-pyro〔1,2-a〕〔1,5〕benzodiazepine-1,2-3-tricarboxylate
WANG HongZhong\ XU JiaXi\ MI BaoYu\ JIN Sheng* (College of Chemistry and Molecular Engineering
结构化学, 1999, (04) : 18 - 22
[10] Crystal Structure of 4-(4-chlorophenyl)-7,7-dimethyl-2,5- dioxo-1,2,3,4,5,6,7,8-octahydroquinoline
TU Shu-Jiang1* ZHOU Jian-Feng2 GAO Yuan3 LIU Xiao-Hong1 1(Department of Chemistry
结构化学, 2001, (06) : 459 - 461

← 1 2 3 4 5 →