One-step electrochemical deposition of nickel sulfide/graphene and its use for supercapacitors

In this current work, the electrochemical co-deposition of nickel sulfide/electrochemically reduced graphene oxide(ERGO) nanocomposites is presented. During the electrochemical process, the graphene oxide nanosheets loose their hydrophilicity and precipitate onto the electrode. In the meantime, nickel sulfide is also electrochemically deposited on the electrode. The porous structure with ERGO covered by nickel sulfide, which facilitates the charge and ion transport in the electrode, has been observed by a scanning electron microscope. The cycle voltammetry curves as well as the galvanostatic charge/discharge curves of the nickel sulfide/ERGO nanocomposites exhibit distinct pseudocapacitive characteristic. The nanocomposites maintain 66.8% of the initial specific capacitance for the first 500 cycles, and only 4.6% loss of the specific capacitance is experienced for the further 1500 cycles, evidently showing a relatively high cycling stability. The results suggest that the nickel sulfide/ERGO is a promising electrode material for supercapacitors. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.