Rate-dependent light-induced thermal hysteresis of [Fe(PM-BiA)2(NCS)2] spin transition complex

被引：21

作者：

Enachescu, Cristian ^{[1
]}

Tanasa, Radu

Stancu, Alexandru

Chastanet, Guillaume

Letard, Jean-Francois

Linares, Jorge

Varret, Francois

机构：

[1] Alexandru Ioan Cuza Univ, Dept Solid State & Theoret Phys, Iasi 700506, Romania

[2] Univ Bordeaux 1, Inst Chim Mat Condensee Bordeaux, Grp Sci Mol, CNRS,UPR 9048, F-33608 Pessac, France

[3] Univ Versailles, Lab Magnetisme & Opt, CNRS, UMR 8634, F-78035 Versailles, France

来源：

JOURNAL OF APPLIED PHYSICS | 2006年 / 99卷 / 08期

关键词：

D O I：

10.1063/1.2167059

中图分类号：

O59 [应用物理学];

学科分类号：

摘要：

The light-induced bistability under permanent irradiation (LITH: light-induced thermal hysteresis), due to the competition between light irradiation and self-accelerated relaxation, shows crucially rate-dependent hysteresis. Major and minor hysteresis loops for [Fe(PM-BiA)(2)(NCS)(2)] spin crossover compound have been measured. Using appropriate master equations, distribution data from the first-order reversal curves diagrams of the purely thermal hysteresis, and parameter values previously derived from relaxation curves, we could simulate the LITH experimental data. The tunneling contribution to the relaxation rate revealed to be a key factor for the final agreement. (C) 2006 American Institute of Physics.

引用

页数：3

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