Single-Crystal Syntheses and Properties of Indium-Organic Frameworks Based on 1,1′-Ferrocenedicarboxylic Acid

被引：13

作者：

Gao, Ran ^{[1
,2
]}

Chen, Shu-Mei ^{[1
]}

Wang, Fei ^{[2
]}

Zhang, Jian ^{[2
]}

机构：

[1] Fuzhou Univ, Coll Chem, Fuzhou 350108, Fujian, Peoples R China

[2] Chinese Acad Sci, Fujian Inst Res Struct Matter, State Key Lab Struct Chem, Fuzhou 350002, Fujian, Peoples R China

来源：

INORGANIC CHEMISTRY | 2021年 / 60卷 / 01期

基金：

美国国家科学基金会;

关键词：

PORE-SPACE PARTITION; COORDINATION POLYMERS; ADSORPTION; SEPARATION; DESIGN; MOF;

D O I：

10.1021/acs.inorgchem.0c02878

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Presented here are a series of indium-organic frameworks synthesized by the self-assembly of In3+ salts and 1,1 '-ferrocenedicarboxylic acid (H(2)FcDCA). Nitrogen-containing organic additives played various roles in the diversity of the structures. These compounds exhibit diverse frameworks with rich supramolecular interactions, which show good photoelectronic and redox activity together with active FcDCA ligands. Moreover, the indium-based MIL-53 analogue exhibited permanent porosity and gas separation.

引用

页码：239 / 245

页数：7

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