Photo-Switching in a Hybrid Material Made of Magnetic Layered Double Hydroxides Intercalated with Azobenzene Molecules

被引：59
作者：
Abellan, Gonzalo [1 ]
Coronado, Eugenio [1 ]
Marti-Gastaldo, Carlos [1 ,3 ]
Ribera, Antonio [1 ]
Luis Jorda, Jose [2 ]
Garcia, Hermenegildo [2 ]
机构：
[1] Univ Valencia, Inst Ciencia Mol, Valencia 46980, Spain
[2] Univ Politecn Valencia, CSIC, Inst Tecnol Quim, Valencia 46022, Spain
[3] Univ Liverpool, Dept Chem, Liverpool L69 7ZD, Merseyside, England
来源：
ADVANCED MATERIALS | 2014年 / 26卷 / 24期
关键词：
AMPHIPHILIC AZOBENZENE; CATIONIC AZOBENZENE; PRUSSIAN BLUE; PHOTOISOMERIZATION; CHROMOPHORES; TEMPERATURE; COEXISTENCE; SIMULATION; MAGADIITE; INTERPLAY;
D O I：
10.1002/adma.201400713
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A magnetic photoresponsive hybrid material is prepared by intercalation of a switchable trans-azobenzene-4,4′-dicarboxylate guest in the interlamellar space offered by a ferromagnetic Co2+Al 3+-layered double hydroxide (LDH) host. Magnetic switching is triggered by compression/modification of the in-plane structure coupled the guest's isomerization causing a change in the magnetization of 27%. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
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收藏
页码：4156 / 4162
页数：7
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