Manganese-Catalyzed and Promoted Reactions of H-Phosphinate Esters

被引：49

作者：

Fisher, Henry C. ^{[1
]}

Berger, Olivier ^{[1
]}

Gelat, Fabien ^{[1
]}

Montchamp, Jean-Luc ^{[1
]}

机构：

[1] Texas Christian Univ, Dept Chem, Ft Worth, TX 76129 USA

来源：

ADVANCED SYNTHESIS & CATALYSIS | 2014年 / 356卷 / 06期

基金：

美国国家科学基金会;

关键词：

H-phosphinates; manganese; phosphorus; phosphorus heterocycles; radical reactions; REGIOSELECTIVE PHOSPHONATION; RADICAL REACTION; P BOND; C-C; ACETATE; SILVER; ALKENES; OXIDES; ARENES;

D O I：

10.1002/adsc.201301157

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

H-Phosphinates react with alkenes and alkynes using catalytic manganese(II) acetate. Under stoichiometric conditions with manganese(III) acetate or with catalytic manganese(II) acetate+excess manganese(II) oxide various reactions like arylation or cyclization through radical oxidative arylation can take place. Whereas the chemistry of manganese is already well developed for the functionalization of H-phosphonates, the present methodology provides an unprecedented access to functionalized phosphinates in acceptable to good yields.

引用

页码：1199 / 1204

页数：6

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