Four Novel Solid-State Supramolecular Assemblies Constructed from Decavanadate Salts and Decamethylcucurbit[5]uril

被引：35

作者：

Kasuga, Noriko Chikaraishi ^{[1
]}

Umeda, Mitsuru ^{[1
]}

Kidokoro, Hajime ^{[1
]}

Ueda, Kazuhiko ^{[1
]}

Hattori, Kenji ^{[1
]}

Yamaguchi, Kazuo ^{[1
]}

机构：

[1] Kanagawa Univ, Fac Sci, Dept Mat Sci, Kanagawa 2591293, Japan

来源：

CRYSTAL GROWTH & DESIGN | 2009年 / 9卷 / 03期

关键词：

METAL-ORGANIC FRAMEWORKS; COMPLEXES; HYBRID; CUCURBITURIL; MOLECULES; VANADIUM; ARCHITECTURES; DERIVATIVES; POLYANIONS; CHEMISTRY;

D O I：

10.1021/cg801007k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The reactions of a barrel-like cyclic host molecule (decamethylcucurbit [5]uril (MeCuc5)) and decavanadate salts (sodium or ammonium decavanadate (M(6)[V(10)O(28)], M = Na(+) or NH(4)(+))) in water at room temperature gave four novel organic-inorganic hybrids, that is, two 2D ladder-like structures, a 1:2 complex, and a one-dimensional infinitely linear chain. Carbonyl oxygen atoms at the portals of the MeCuc5 molecules coordinate to cations (Na(+) or NH(4)(+)) at the center or corner of the portals, and the resulting cationic organic species and decavanadate anions (HV(10)O(28)(5-) and H(2)V(10)O(28)(4-)) interact though electrostatic interaction and hydrogen bonds in the crystals.

引用

页码：1494 / 1498

页数：5

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