Vibrational imaging of a J-aggregate microcrystal using ultrabroadband multiplex coherent anti-Stokes Raman scattering microspectroscopy

被引:3
作者
Kano, Hideaki [1 ]
Hamaguchi, Hiro-o [1 ]
机构
[1] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan
基金
日本学术振兴会;
关键词
J-aggregate; multiplex; coherent anti-Stokes Raman scattering; CARS; supercontinuum; photonic crystal fiber;
D O I
10.1016/j.vibspec.2006.01.001
中图分类号
O65 [分析化学];
学科分类号
070302 ; 081704 ;
摘要
Vibrational properties of a porphyrin J-aggregate microcrystal have been investigated by ultrabroadband multiplex coherent anti-Stokes Raman scattering (CARS) microspectroscopy using a supercontinuum generated from a photonic crystal fiber. Owing to a strong resonance effect due to an excitonic transition, clear spectral and spatial profiles of the CARS signal have been successfully obtained. The multiplex CARS image indicates a rod-like microcrystal, which agrees well with the microscopic image and the atomic force microscopy studies. (C) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:135 / 139
页数:5
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