Bis(1,10-phenanthroline-κ2N,N′)(squarato-κO)copper(II) trihydrate

被引：32

作者：

Bulut, A ^{[1
]}

Uçar, I

Yesilel, OZ

Içbudak, H

Ölmez, H

Büyükgüngör, O

机构：

[1] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Phys, TR-55139 Kurupelit, Turkey

[2] Ondokuz Mayis Univ, Fac Arts & Sci, Dept Chem, TR-55139 Kurupelit, Turkey

来源：

ACTA CRYSTALLOGRAPHICA SECTION C-STRUCTURAL CHEMISTRY | 2004年 / 60卷

关键词：

D O I：

10.1107/S0108270104020566

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The title mononuclear [Cu(sq)(phen)(2)] . 3H(2)O complex [ sq is squarate (C4O4) and phen is 1,10-phenanthroline (C12H8N2)] has been synthesized and the structure consists of a neutral mononuclear [ Cu( sq)( phen) 2] unit and three solvate water molecules. The Cu-II ion has distorted square-pyramidal coordination geometry, comprised of one carboxylate O atom from a monodentate squarate ligand and four N atoms from two chelating phen ligands. An extensive three-dimensional network of OW - H ... O/OW hydrogen bonds, face-to-face pi-pi interactions between the 1,10-phenanthroline aromatic rings and a weak pi-ring interaction are responsible for crystal stabilization.

引用

页码：M526 / M528

页数：3

共 38 条

[1] SIR97:: a new tool for crystal structure determination and refinement [J].

Altomare, A ;

Burla, MC ;

Camalli, M ;

Cascarano, GL ;

Giacovazzo, C ;

Guagliardi, A ;

Moliterni, AGG ;

Polidori, G ;

Spagna, R .

JOURNAL OF APPLIED CRYSTALLOGRAPHY, 1999, 32 :115-119

[2] VERSATILITY OF SQUARIC ACID AS LIGAND - CRYSTAL, MOLECULAR-STRUCTURES AND MAGNETIC STUDIES OF 4 POLYMETALLIC OR DIMETALLIC CU(II) COMPLEXES [J].

BERNARDINELLI, G ;

DEGUENON, D ;

SOULES, R ;

CASTAN, P .

CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE, 1989, 67 (07) :1158-1165

[3]

Burnett M.N., 1996, ORTEP-III: Oak Ridge Thermal Ellipsoid Plot Program for Crystal Structure Illustrations

[4] INTERACTIONS OF SQUARIC AND CROCONIC ACIDS WITH [PTL4](2+) COMPLEXES (L = NH3, L2 = ETHYLENEDIAMINE) - OXIDATIVE PROPERTIES OF OXOCARBON ACIDS AND CRYSTAL-STRUCTURE DETERMINATIONS [J].

CASTAN, P ;

DEGUENON, D ;

FABRE, PL .

POLYHEDRON, 1992, 11 (08) :901-908

[5] Synthesis, chemical characterization and crystal structure of the (oxalato-O,O′)bis(1,10-phenanthroline)copper(II) pentahydrate [J].

Castillo, O ;

Luque, A ;

Román, P .

JOURNAL OF MOLECULAR STRUCTURE, 2001, 570 (1-3) :181-188

[6] Crystal structures and magnetic properties of the squarate-O1,On-bridged dinuclear copper(II) complexes [Cu2(phen)4(C4O4)](CF3SO3)2•3H2O (n = 2) and [Cu2(bipy)4(C4O4)](CF3SO3)2•6H2O (n = 3) [J].

Castro, I ;

Calatayud, ML ;

Sletten, J ;

Lloret, F ;

Julve, M .

INORGANICA CHIMICA ACTA, 1999, 287 (02) :173-180

[7]

Claessens CG, 1997, J PHYS ORG CHEM, V10, P254, DOI 10.1002/(SICI)1099-1395(199705)10:5<254::AID-POC875>3.0.CO

[8]

2-3

[9] Synthesis and crystal structure of dinuclear cyclopalladated 1,2-and 1,3-bridged squarato complexes [J].

Crispini, A ;

Pucci, D ;

Aiello, I ;

Ghedini, M .

INORGANICA CHIMICA ACTA, 2000, 304 (02) :219-223

[10] SUPRAMOLECULAR SYNTHONS IN CRYSTAL ENGINEERING - A NEW ORGANIC-SYNTHESIS [J].

DESIRAJU, GR .

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION IN ENGLISH, 1995, 34 (21) :2311-2327

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