Molecular design approach to a stable heterometallic zirconium-titanium alkoxide - potential precursor of mixed-oxide ceramics

被引：21
作者：
Spijksma, GI
Bouwmeester, HJM
Blank, DHA
Kessler, VG
机构：
[1] SLU, Dept Chem, S-75007 Uppsala, Sweden
[2] Univ Twente, Fac Sci & Technol, NL-7500 AE Enschede, Netherlands
[3] Univ Twente, Mesa & Res Inst Nanotechnol, NL-7500 AE Enschede, Netherlands
来源：
INORGANIC CHEMISTRY COMMUNICATIONS | 2004年 / 7卷 / 08期
关键词：
heterometallic alkoxides; X-ray structure; nona-coordinated zirconium;
D O I：
10.1016/j.inoche.2004.06.006
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
New heterometallic interesting trinuclear, Zr{eta(3), mu(2)-NH(c(2)H(4)O(2)}(3)[Ti((OPr)-Pr-i)(3)](2) encountering a nona-coordinated central zirconium atom crystallizes at -30 degreesC from a solution of zirconium and titanium isopropoxides and diethanolamine (Zr:Ti:L = 1:23) in hydrocarbons. Due to its solution stability, this structurally characterized compound is an attractive potential precursor in sol-gel technique for the preparation of mixed metal oxide materials. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：953 / 955
页数：3
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