Solvent effect on the kinetics of the free-radical polymerization of styrene in the presence of fullerene C60

被引：3

作者：

Yumagulova, R. Kh. ^{[1
]}

Medvedeva, N. A. ^{[1
]}

Kuznetsov, S. I. ^{[1
]}

Kraikin, V. A. ^{[1
]}

Kolesov, S. V. ^{[1
]}

机构：

[1] Russian Acad Sci, Ufa Sci Ctr, Inst Organ Chem, Ufa 450054, Bashkortostan, Russia

来源：

KINETICS AND CATALYSIS | 2014年 / 55卷 / 01期

关键词：

METHYL-METHACRYLATE; SOLUBILITY; C-70;

D O I：

10.1134/S0023158414010182

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

The induction period in the kinetic curves of styrene polymerization in the presence of fullerene C-60 was found to increase significantly at a solvent (benzene, toluene, ortho-dichlorobenzene, CCl4) concentration of a parts per thousand yen50 mol %. The free-radical polymerization rates of styrene in the presence of fullerene C-60 and solvents, the ratio of chain propagation and termination rate constants k (p) /k (0) (1/2) , and the stoichiometric inhibition coefficient were determined.

引用

页码：64 / 68

页数：5

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