X-ray induced effects in phosphate glasses

被引：95
作者：
Ebeling, P
Ehrt, D
Friedrich, M
机构：
[1] Univ Jena, Otto Schott Inst, D-07743 Jena, Germany
[2] Inst Inorgan & Analyt Chem, D-07743 Jena, Germany
来源：
OPTICAL MATERIALS | 2002年 / 20卷 / 02期
关键词：
phosphate glasses; irradiation; defects; optical absorption; electron paramagnetic resonance;
D O I：
10.1016/S0925-3467(02)00052-6
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Optical absorption and paramagnetic resonance spectra of X-ray irradiated (lambda(CuKalpha), = 0.154 nm) ultra- and metaphosphate glasses of high purity were studied. Melting of the samples under different redox conditions, investigation of annealing behavior of the irradiated samples and correlation between optical and EPR spectra allowed the resolution of five main paramagnetic radiation-induced defects and associated optical absorption bands. Phosphorus and oxygen related radiation-induced defects were found, with hole centers POHC and OHC absorbing in the visible and electron trapped centers PO2, PO3 and PO4 absorbing in the ultraviolet region. (C) 2002 Elsevier Science B,V. All rights reserved.
引用
收藏
页码：101 / 111
页数：11
相关论文
共 22 条
[11]   FUNDAMENTAL DEFECT CENTERS IN GLASS - ELECTRON-SPIN RESONANCE AND OPTICAL-ABSORPTION STUDIES OF IRRADIATED PHOSPHORUS-DOPED SILICA GLASS AND OPTICAL FIBERS [J].
GRISCOM, DL ;
FRIEBELE, EJ ;
LONG, KJ ;
FLEMING, JW .
JOURNAL OF APPLIED PHYSICS, 1983, 54 (07) :3743-3762
[12]   COMPUTER-SIMULATION ANALYSIS OF THE ESR-SPECTRA OF V-TYPE CENTERS IN IRRADIATED HEAVY-METAL FLUORIDE GLASSES [J].
GRISCOM, DL ;
FRIEBELE, EJ .
PHYSICAL REVIEW B, 1991, 43 (10) :7427-7441
[13]  
GRISCOM DL, 1971, J NONCRYST SOLIDS, V6, P257
[14]   ELECTRON-SPIN-RESONANCE STUDY OF RADIATION-INDUCED PARAMAGNETIC DEFECT CENTERS LOCALIZED ON A PHOSPHORUS IN BINARY PHOSPHATE-GLASSES [J].
HOSONO, H ;
ABE, Y ;
KAWAZOE, H .
JOURNAL OF NON-CRYSTALLINE SOLIDS, 1985, 71 (1-3) :261-267
[15]  
JUDIN DM, 1965, FIZ TVERD TELA, V7, P1731
[16]  
KAWAZOE H, 1986, MATER RES SOC S P, V61, P339
[17]   ESR STUDIES OF RADIATION PROCESSES IN PHOSPHATE GLASSES [J].
KOLDITZ, L ;
SCHMIDT, H ;
WOLF, M ;
STOSSER, R .
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 1974, 405 (03) :286-298
[18]   REACTOR AND GAMMA-RAY INDUCED COLORING OF CORNING FUSED SILICA [J].
LEVY, PW .
JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1960, 13 (3-4) :287-295
[19]   THE KINETICS OF GAMMA-RAY INDUCED COLORING OF GLASS [J].
LEVY, PW .
JOURNAL OF THE AMERICAN CERAMIC SOCIETY, 1960, 43 (08) :389-395
[20]  
MARION JE, 1991, EUR J SOL STATE INOR, V28, P271
123