X-ray induced effects in phosphate glasses

被引：95

作者：

Ebeling, P

Ehrt, D

Friedrich, M

机构：

[1] Univ Jena, Otto Schott Inst, D-07743 Jena, Germany

[2] Inst Inorgan & Analyt Chem, D-07743 Jena, Germany

来源：

OPTICAL MATERIALS | 2002年 / 20卷 / 02期

关键词：

phosphate glasses; irradiation; defects; optical absorption; electron paramagnetic resonance;

D O I：

10.1016/S0925-3467(02)00052-6

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Optical absorption and paramagnetic resonance spectra of X-ray irradiated (lambda(CuKalpha), = 0.154 nm) ultra- and metaphosphate glasses of high purity were studied. Melting of the samples under different redox conditions, investigation of annealing behavior of the irradiated samples and correlation between optical and EPR spectra allowed the resolution of five main paramagnetic radiation-induced defects and associated optical absorption bands. Phosphorus and oxygen related radiation-induced defects were found, with hole centers POHC and OHC absorbing in the visible and electron trapped centers PO2, PO3 and PO4 absorbing in the ultraviolet region. (C) 2002 Elsevier Science B,V. All rights reserved.

引用

页码：101 / 111

页数：11

共 22 条

[1]

BARINOVA NA, 1990, FIZ KHIM STEKLA, V16, P788

[2]

DMITRYUK AV, 1990, FIZ KHIM STEKLA, V16, P910

[3]

Ebeling P, 2000, GLASS SCI TECHNOL, V73, P156

[4]

Ebeling P., 1999, PHOSPHORUS RES B, V10, P484

[5]

EBELING P, THESIS U JENA GERMAN

[6]

EBENDORFFHEIDEP.H, 1999, P 73 DGG M 31 MAY 2, P126

[7] Redox behaviour of polyvalent ions in the ppm range [J].

Ehrt, D .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1996, 196 :304-308

[8] HIGH-PERFORMANCE GLASS FOR THE DEEP-ULTRAVIOLET RANGE [J].

EHRT, D ;

CARL, M ;

KITTEL, T ;

MULLER, M ;

SEEBER, W .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 1994, 177 (pt 1) :405-419

[9] UV Transmission and radiation-induced defects in phosphate and fluoride-phosphate glasses [J].

Ehrt, D ;

Ebeling, P ;

Natura, U .

JOURNAL OF NON-CRYSTALLINE SOLIDS, 2000, 263 (1-4) :240-250

[10]

EHRT D, 1992, NUCL INSTRUMENTS MET, P1

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