Studies on the nanotubes formed by 2-phenyl-5-(4-diphenylyl)1,3,4-oxadiazole and cyclodextrins

被引：24
|
作者：
Zhang, CF [1 ]
Shen, XH [1 ]
Gao, HC [1 ]
机构：
[1] Peking Univ, Coll Chem & Mol Engn, Inst Appl Chem, Beijing 100871, Peoples R China
来源：
CHEMICAL PHYSICS LETTERS | 2002年 / 363卷 / 5-6期
基金：
中国国家自然科学基金;
关键词：
D O I：
10.1016/S0009-2614(02)01206-X
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
We report herein the interaction of 2-phenyl-5-(4-diphenylyl) 1,3,4-oxadiazole (PBD) with alpha-, beta-, and gamma-cyclodextrins (CDs). It was found that the reaction patterns between PBD and CDs are remarkably different. alpha-CD can form a simple 1:2 (guest:host) inclusion complex with PBD, while beta-CD and gamma-CD can form nanotube with PBD at higher concentration of both PBD and CDs. It was also found that the interaction pattern of butyl-2-(4-biphenylyl)-5-(4-tert-butylphenyl)-1,3,4-oxadiazole (butyl-PBD) with CDs is similar to that of PBD with CDs. On the basis of the above results, possible structures of these cyclodextrin nanotubes were discussed. (C) 2002 Elsevier Science B.V. All rights reserved.
引用
收藏
页码：515 / 522
页数：8
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