Energy-Efficient Green Catalysis: Supported Gold Nanoparticle-Catalyzed Aminolysis of Esters with Inert Tertiary Amines by C-O and C-N Bond Activations

被引：42
作者：
Bao, Yong-Sheng [1 ]
Baiyin, Menghe [1 ]
Agula, Bao [1 ]
Jia, Meilin [1 ]
Bao Zhaorigetu [1 ]
机构：
[1] Inner Mongolia Normal Univ, Coll Chem & Environm Sci, Inner Mongolia Key Lab Green Catalysis, Hohhot 010022, Peoples R China
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2014年 / 79卷 / 14期
关键词：
PALLADIUM NANOPARTICLES; COUPLING REACTIONS; OXIDE SUPPORTS; OXIDATION; ALDEHYDES; CARBENE; REDUCTION; LIGHT; AMIDE;
D O I：
10.1021/jo500877m
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Catalyzed by supported gold nanoparticles, an aminolysis reaction between various aryl esters and inert tertiary amines by C-O and C-N bond activations has been developed for the selective synthesis of tertiary amides. Comparison studies indicated that the gold nanoparticles could perform energy-efficient green catalysis at room temperature, whereas Pd(OAc)(2) could not.
引用
收藏
页码：6715 / 6719
页数：5
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