Synthesis and crystal structure of [P(C6H5)(4)](2)[2-SnCl2(C6H5)B10H9]

被引：0

作者：

Nachtigal, C ^{[1
]}

Preetz, W ^{[1
]}

机构：

[1] CHRISTIAN ALBRECHTS UNIV KIEL,INST ANORGAN CHEM,D-24098 KIEL,GERMANY

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 1997年 / 52卷 / 08期

关键词：

2-(dichlorophenyltin)-nonahydro-closo-decaborate(2-); crystal structure;

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

By reaction of [N(C4H9)(4)](2)[B10H10] with dichlorodiphenyltin in acetonitril at 80 degrees C the 2-(dichlorophenyltin)-decaborate anion [2-SnCl2(C6H5)B10H9](2-) is formed and can be isolated by ion exchange chromatography on diethylaminoethyl(DEAE) cellulose. The X-ray structure of [P(C6H5)(4)](2)[2-SnCl2(C6H5)B10H9] (triclinic, space group P (1) over bar with a = 11.2342(11), b = 11.2549(13), c = 22.265(6) Angstrom, alpha = 89.478(14), beta = 84.511(13), gamma = 74.049(8)degrees) reveals that the SnCl2(C6H5) substituent is bonded with a B2-Sn distance of 2.182(6) Angstrom.

引用

页码：975 / 977

页数：3