Mixing Polyaromatic Scaffolds and Main Group Elements: Synthesis, Coordination and Optical Properties of Naphthyl-Fused Heteropines

被引：9

作者：

Delouche, Thomas ^{[1
]}

Roisnel, Thierry ^{[1
]}

Dorcet, Vincent ^{[1
]}

Hissler, Muriel ^{[1
]}

Bouit, Pierre-Antoine ^{[1
]}

机构：

[1] Univ Rennes, CNRS, ISCR UMR 6226, F-35000 Rennes, France

来源：

EUROPEAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 2021卷 / 11期

关键词：

Fluorescence; Germanium; Heterocycles; Phosphorus; Pi-systems; WARPED NANOGRAPHENE; DERIVATIVES; REACTIVITY; COMPLEXES; ROUTE;

D O I：

10.1002/ejic.202001097

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

In this article, we describe the synthesis of polyaromatic heteropines including main group element (Phosphorus, Germanium) through Ni or Cu-mediated C-C coupling. Coordination complexes were synthesized with the sigma(3),lambda(3)-phosphepines using different metal ions (Au(I), Re(I), Pd(II)) showing that these P-heterocycles display the classical reactivity of two-electrons P-donor making them promising ligands. The optical properties were experimentally studied (UV-vis absorption and emission) and compared. Finally, both polyaromatic germepine and phosphepine appear as interesting building blocks for optoelectronics.

引用

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页码：1082 / 1089

页数：8

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