Spectroscopic properties and frequency upconversion of Er3+-doped 0.8CaSiO3-0.2Ca3(PO4)2 eutectic glass

被引:15
作者
Balda, R. [1 ,2 ,3 ]
Merino, R. I. [4 ]
Pena, J. I. [4 ]
Orera, V. M. [4 ]
Arriandiaga, M. A. [5 ]
Fernandez, J. [1 ,2 ,3 ]
机构
[1] Escuela Super Ingn, Dpto Fis Aplicada 1, Bilbao 48013, Spain
[2] CSIC UPV EHU, Unidad Fis Mat, San Sebastian 20080, Spain
[3] Donostia Int Phys Ctr, San Sebastian 20080, Spain
[4] Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Fac Ciencias, E-50009 Zaragoza, Spain
[5] Univ Basque Country, Fac Ciencias & Tecnol, Dpto Fis Aplicada 2, E-48080 Bilbao, Spain
关键词
Upconversion; Eutectic glasses; Optical materials; Rare-earth; MULTIPHONON RELAXATION; LASER; ER3+; IONS; EMISSION;
D O I
10.1016/j.optmat.2008.01.019
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
In this work we report the spectroscopic properties of the infrared emission at 1.5 mu m and the infrared to visible upconversion processes in Er3+-doped glasses with the 0.8CaSiO(3)-0.2Ca(3)(PO4)(2) eutectic composition. Intense upconversion green emissions at 529 and 550 nm have been observed under infrared excitation at 800 nm in the I-4(9/2) level and attributed to a two photon upconversion process. The possible excitation mechanisms responsible for this upconversion luminescence are discussed in terms of excitation spectrum and time evolution of the upconverted luminescence. The time evolution of the green emission from the S-4(3/2) level indicates that an ETU process is responsible for the upconversion luminescence. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码:1105 / 1108
页数:4
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