Recent developments in C-H functionalization via C-H bond activation using ball milling and transition-metal catalysts

被引：18
|
作者：
Ranu, Brindaban C. [1 ]
Ghosh, Tubai [1 ]
Jalal, Swapnadeep [1 ]
机构：
[1] Indian Assoc Cultivat Sci, Sch Chem Sci, Kolkata 700032, India
来源：
ARKIVOC | 2019年
关键词：
C-H functionalization; C-H bond activation; ball milling; green chemistry; mechanochemistry; MECHANOCHEMISTRY; AMIDATION; PATHWAYS;
D O I：
10.24820/ark.5550190.p010.862
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The inert C-H bond functionalization via bond activation in the presence of transition metals using ball milling is reviewed. The use of several transition metals, such as Pd, Rh, Ru, Co, and Ir are covered in this review for a variety of important functionalizations, including halogenation, amidation, alkynylation, and dehydrogenative coupling, among others. These reactions are performed under mild conditions, usually without any solvent, and in relatively short reaction times. [GRAPHICS] .
引用
收藏
页码：79 / 92
页数：14
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