Thermodynamic properties of binary mixtures of p-xylene with cyclohexane, heptane, octane, and N-methyl-2-pyrrolidone at several temperatures

被引:115
作者
Yang, CS [1 ]
Xu, W [1 ]
Ma, PS [1 ]
机构
[1] Tianjin Univ, Sch Chem Engn & Technol, State Educ Minist, Key Lab Green Chem Technol, Tianjin 300072, Peoples R China
关键词
D O I
10.1021/je049776w
中图分类号
O414.1 [热力学];
学科分类号
摘要
Densities and viscosities for p-xylene with cyclohexane, heptane, octane, and N-methyl-2-pyrrolidone were determined from (298.15 to 353.15) K and at atmospheric pressure. The measurements were carried out over the whole range of composition, using a vibrating-tube density meter and a Ubbelohde viscometer. Density and viscosity measurements were used to compute the excess molar volumes, V-E, and viscosity deviations, Deltaeta. The excess molar volumes, V-E, and viscosity deviations, Deltaeta, have been fit to the Redlich-Kister equation, and the coefficients and estimates of the standard error values are given.
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页码:1794 / 1801
页数:8
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