Radical addition polymerisation of acrylates in a buss-kneader

被引：5

作者：

Troelstra, EJ

Dierendonck, LLV

Janssen, LPBM

Maeder, S

Renken, A

机构：

[1] ECOLE POLYTECH FED LAUSANNE,INST GENIE CHIM,CH-1015 LAUSANNE,SWITZERLAND

[2] UNIV GRONINGEN,DEPT CHEM ENGN,9747 AG GRONINGEN,NETHERLANDS

来源：

CHEMICAL ENGINEERING SCIENCE | 1996年 / 51卷 / 10期

关键词：

D O I：

10.1016/0009-2509(96)00105-4

中图分类号：

TQ [化学工业];

学科分类号：

0817 ;

摘要：

The radical addition co-polymerisation of 2-hydroxyethylmethacrylate and butylacrylate is carried out in a continuously operating Buss-Kneader. To calculate temperature profiles over the length of the kneader the heat balance is solved. For the heat transfer coefficient a model based on the penetration theory is used. This model is experimentally verified. The reaction kinetics of the radical addition polymerisation are studied in a differential scanning calorimeter. The polymerisation kinetics are modeled using non-stationary radical concentrations. The calculated temperature profiles over the length of the Buss-Kneader are a good approximation of the experimental data.

引用

页码：2479 / 2488

页数：10

共 11 条

[1]

AEPPLI HD, 1989, PLASTVERARBEITER, V40, P108

[2]

Elemans P., 1989, THESIS TU EINDHOVEN

[3]

FLEURY PA, 1993, THESIS EPF LAUSANNE

[4]

FRANZ P, 1988, KUNSTSTOFFTECHNIK PO, P210