Morphology and physico-electrochemical properties of poly(aniline-co-pyrrole)

被引：35

作者：

Xu, P. ^{[1
]}

Han, X. J. ^{[1
]}

Wang, C. ^{[1
]}

Zhang, B. ^{[1
]}

Wang, H-L. ^{[2
]}

机构：

[1] Harbin Inst Technol, Dept Chem, Harbin 150001, Peoples R China

[2] Los Alamos Natl Lab, Div Chem, Los Alamos, NM 87545 USA

来源：

SYNTHETIC METALS | 2009年 / 159卷 / 5-6期

关键词：

Polyaniline; Polypyrrole; Copolymer; Morphology; Cyclic voltammetry; POLYPYRROLE COMPOSITE COATINGS; POLYANILINE NANOFIBERS; FACILE SYNTHESIS; TEMPLATELESS; DEPOSITION; POLYMERS;

D O I：

10.1016/j.synthmet.2008.10.016

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

Copolymers of aniline (An) and pyrrole (Py), poly(aniline-co-pyrrole), have been prepared by a conventional chemical oxidative polymerization from monomer Mixtures of various compositions, with ammonium persulfate (APS) as the oxidant and hydrochloric acid as the dopant, and the morphologies and physico-electrochemical properties of the poly(aniline-co-pyrrole) have been investigated. Poly(aniline-co-pyrrole) prepared with more polyaniline (PANI) or polypyrrole (PPy) component have similar morphologies, structures, thermal and electrochemical performances, and the relative dosage (molar ratio) of An and Py monomers during the polymerization is crucial to the properties of the resulting poly(aniline-co-pyrrole). More monomer applied in the polymerization of An and Py mixtures would result in products with similar properties to the individual homopolymer of that monomer, while poly(aniline-co-pyrrole) prepared from equimolar An and Py monomer displays unique properties. The conductivity is a non-linear function of chemical composition, and this chemical heterogeneity might lead to the broad DSC curves and various morphologies of the poly(aniline-co-pyrrole) copolymers. (C) 2008 Elsevier B.V. All rights reserved.

引用

页码：430 / 434

页数：5

共 34 条

[1] Electrochemical deposition of polyaniline-polypyrrole composite coatings on aluminum [J].

Akundy, GS ;

Rajagopalan, R ;

Iroh, JO .

JOURNAL OF APPLIED POLYMER SCIENCE, 2002, 83 (09) :1970-1977

[2] Polyaniline and polypyrrole:: A comparative study of the preparation [J].

Blinova, Natalia V. ;

Stejskal, Jaroslav ;

Trchova, Miroslava ;

Prokes, Jan ;

Omastova, Maria .

EUROPEAN POLYMER JOURNAL, 2007, 43 (06) :2331-2341

[3]

Cha SK, 1997, J POLYM SCI POL PHYS, V35, P165

[4] Self-assembled polyaniline nanofibers/nanotubes [J].

Chiou, Nan-Rong ;

Lee, L. James ;

Epstein, Arthur J. .

CHEMISTRY OF MATERIALS, 2007, 19 (15) :3589-3591

[5] A novel templateless method to nanofibers of polyaniline derivatives with size control [J].

Han, Jie ;

Liu, Yan ;

Guo, Rong .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2008, 46 (02) :740-746

[6] Study of the effects of nanometer β-Ni(OH)2 in nickel hydroxide electrodes [J].

Han, XJ ;

Xu, P ;

Xu, CQ ;

Zhao, L ;

Mo, ZB ;

Liu, T .

ELECTROCHIMICA ACTA, 2005, 50 (14) :2763-2769

[7]

Hoang H.V., 2006, CHEM MATER, V18, P1976

[8] Electrochemistry of conductive polymers 36. pH dependence of polyaniline conductivities studied by current-sensing atomic force microscopy [J].

Hong, SY ;

Park, SM .

JOURNAL OF PHYSICAL CHEMISTRY B, 2005, 109 (19) :9305-9310

[9] Templateless and surfactantless route to the synthesis of polyaniline nanofibers [J].

Li, GC ;

Pang, SP ;

Peng, HR ;

Wang, ZB ;

Cui, ZL ;

Zhang, ZK .

JOURNAL OF POLYMER SCIENCE PART A-POLYMER CHEMISTRY, 2005, 43 (17) :4012-4015

[10] Synthesis of dendritic polyaniline nanofibers in a surfactant gel [J].

Li, GC ;

Zhang, ZK .

MACROMOLECULES, 2004, 37 (08) :2683-2685

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